cyclopenta-1,3-diene;diphenylphosphanylmethyl(diphenyl)phosphane;oxolane-2-thione;ruthenium(2+);hexafluorophosphate | 166670-08-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: cyclopenta-1,3-diene;diphenylphosphanylmethyl(diphenyl)phosphane;oxolane-2-thione;ruthenium(2+);hexafluorophosphate
• CAS: 166670-08-2
• 化学式: C₃₄H₃₃OP₂RuS*F₆P
• 分子量: 797.683
• InChiKey: KFODQDYTRVMOHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium 、 thiobutyrolactone 以 丙酮 为溶剂， 以87%的产率得到cyclopenta-1,3-diene;diphenylphosphanylmethyl(diphenyl)phosphane;oxolane-2-thione;ruthenium(2+);hexafluorophosphate
  参考文献：
  名称：

  Synthesis and vibrational spectra of thiobutyrolactone and thiono-benzonaphthopyranones and their cyclopentadienyl ruthenium complexes

  摘要：

  The preparation of the thiobutyrolactone complexes [Cp(dppx)Ru-1]PF6 with dppx = dppm (la) and dppe (Ib) is described. Raman spectra of the polycrystalline solids and the CH2Cl2 solutions were recorded by means of the scanning multichannel technique and charge-coupled device detection. The results are reported with complementary IR data. Vibrational assignments are proposed for the compounds and the carbon-sulfur stretching vibrations have been assigned by means of polarized Raman measurements, Likewise, spectra of thiono-benzonaphthopyranones 2-4 and their complexes were recorded. Assignments are given for the lactones themselves and their ruthenium complexes.

  DOI：

  10.1016/0022-328x(95)05304-8