cyclopentanone dibutyl ketal | 106679-16-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cyclopentanone dibutyl ketal
• 英文别名: 1,1-di-n-butoxycyclopentane；1,1-dibutoxycyclopentane
• CAS: 106679-16-7
• 化学式: C₁₃H₂₆O₂
• 分子量: 214.348
• InChiKey: ZIPJNBDDQVHKBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-(3,5-dichlorophenylthio)-4-isopropyl-2-(2-hydroxyethyl)-1-methyl-1H-imidazole 、 cyclopentanone dibutyl ketal 以29.3%的产率得到5-(3,5-Dichlorophenylthio)-4-isopropyl-2-[2-(1-n-butoxycyclopentyloxy)ethyl]-1-methyl-1H-imidazole
  参考文献：
  名称：

  Lymph-absorbable aryl substituted imidazole derivatives

  摘要：

  公式（I）的化合物：##STR1##及其盐或水合物，可以有效地从肠道的淋巴管吸收，并以高浓度转移到淋巴结。

  公开号：

  US06054591A1
• 作为产物：
  描述：

  环戊酮 、 正丁醇 在 对甲苯磺酸 、 原甲酸三乙酯 作用下， 生成 cyclopentanone dibutyl ketal
  参考文献：
  名称：

  外用驱蚊剂。3.羧酰胺缩醛和缩酮以及相关的羰基加成衍生物。

  摘要：

  DOI：

  10.1002/jps.2600600116

文献信息

• Photocurable coating composition, laminate, and automotive headlamp covering sheet
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2865720A1

  公开（公告）日：2015-04-29

  A photocurable coating composition is provided comprising (1) surface-treated titanium oxide comprising core/shell type microparticles each consisting of a titanium oxide core and a silicon oxide shell, which are treated with two surface treating components having formula (I): R1Si(OR2)3 wherein R1 is an organic group which may have a (meth)acrylic moiety, and R2 is alkyl, and formula (II): (R3R4 2Si)2NH wherein R3 is an organic group which may have a (meth)acrylic moiety, and R4 is alkyl, (2) a photopolymerizable monomer or oligomer, and (3) a photoinitiator. The composition has good transparency and mar resistance despite titanium oxide loading.

  本发明提供了一种光固化涂层组合物，包括(1)表面处理过的氧化钛，该氧化钛由核/壳型微粒组成，每个微粒都由氧化钛核和氧化硅壳组成，并用两种表面处理成分进行处理，这两种表面处理成分具有式(I)：R1Si(OR2)3 其中 R1 是有机基团，可以是(甲基)丙烯酸基团，R2 是烷基，和式 (II)：(R3R4 2Si)2NH 其中 R3 是有机基团，可以是(甲基)丙烯酸基团，R4 是烷基，(2) 可光聚合的单体或低聚物，和 (3) 光引发剂。尽管添加了氧化钛，该组合物仍具有良好的透明度和耐磨性。
• Titania-containing coating composition and coated article
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2868717A1

  公开（公告）日：2015-05-06

  A coating composition is provided comprising (A) 1-50 parts by weight of surface-treated titanium oxide comprising core/shell type microparticles each consisting of a titanium oxide core and a silicon oxide shell, which are treated with two surface treating components having formula (I): R1Si(OR2)3 and formula (II): (R3R42Si)2NH, (B) 100 parts by weight of a vinyl copolymer obtained from copolymerization of (b-1) an alkoxysilyl-containing vinyl monomer, (b-2) a UV-absorbing vinyl monomer, and (b-3) another monomer, and (C) a solvent. A cured film of the composition has improved mar resistance and UV shielding while maintaining visible light transparency.

  提供了一种涂层组合物，它包括(A)1-50 份(重量)经表面处理的氧化钛，这些氧化钛由核/壳型微粒组成，每个微粒由氧化钛核和氧化硅壳组成，这些微粒经两种表面处理成分处理，这两种表面处理成分分别为式(I)：R1Si(OR2)3 和式 (II)：(R3R42Si)2NH，(B) 100 重量份的乙烯基共聚物，由(b-1)含烷氧基硅烷的乙烯基单体、(b-2)紫外线吸收乙烯基单体和(b-3)另一种单体共聚而成，以及(C)溶剂。该组合物固化后的薄膜具有更好的抗磨损性和紫外线屏蔽性，同时还能保持可见光的透明度。
• ORGANIC SOLVENT DISPERSION OF TITANIUM OXIDE SOLID-SOLUTION PARTICLES, MAKING METHOD AND COATING COMPOSITION
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2933230A1

  公开（公告）日：2015-10-21

  Core/shell type tetragonal titanium oxide solid-solution particles each consisting of a core of tetragonal titanium oxide having tin and manganese incorporated in solid solution and a shell of silicon oxide are dispersed in an organic solvent. The core/shell type particles have a diameter D50 of 5-50 nm. The amount of tin incorporated in solid solution is to provide a molar ratio Ti/Sn of 10-1,000, and the amount of manganese incorporated in solid solution is to provide a molar ratio Ti/Mn of 10-1,000.

  核/壳型四角氧化钛固溶体颗粒分散在有机溶剂中，每个颗粒都由固溶体中含有锡和锰的四角氧化钛核和氧化硅壳组成。芯/壳型颗粒的直径 D50 为 5-50 纳米。在固溶体中加入的锡量是为了提供 10-1,000 的钛/锰摩尔比，在固溶体中加入的锰量是为了提供 10-1,000 的钛/锰摩尔比。
• TITANIUM OXIDE SOLID SOLUTION DISPERSION AND COATING COMPOSITION
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2952480A1

  公开（公告）日：2015-12-09

  A dispersion in organic solvent of a core-shell type tetragonal titanium oxide solid solution in which a core is composed of a tetragonal titanium oxide microparticle containing at least one element (M0) selected from the group consisting of gallium, vanadium, niobium, tantalum, zirconium, aluminum, and indium in the solid solution and containing tin in the solid solution, and a shell surrounding the core is composed of silicon oxide. The core-shell type solid solution has a particle diameter (D50) corresponding to 50% in volume-based cumulative particle size distribution as measured by a dynamic light scattering method using a laser beam of up to 50 nm, the amount of the tin component dissolved in the solid solution, expressed in molar ratio (Ti/Sn) of titanium to tin, is in the range from 10 to 1,000, and the total amount of the (M0) component dissolved in the solid solution, expressed in molar ratio (Ti/M0) of titanium to (M0), is in the range from 10 to 1,000.

  一种核壳型四方氧化钛固溶体在有机溶剂中的分散体，其核由四方氧化钛微粒子组成，该微粒子含有至少一种选自镓、钒、铌、钽、锆、铝和铟组成的组中的元素（M0），并在固溶体中含有锡，环绕核的壳由氧化硅组成。核壳型固溶体的粒径（D50）相当于用激光束动态光散射法测得的基于体积的累积粒度分布的 50%，粒径最大为 50 纳米，溶解在固溶体中的锡成分的量、以钛与锡的摩尔比 (Ti/Sn) 表示的溶解在固溶体中的锡成分的量在 10 至 1,000 之间，以钛与 (M0) 的摩尔比 (Ti/M0) 表示的溶解在固溶体中的 (M0) 成分的总量在 10 至 1,000 之间。
• Rhenium complex-catalyzed allylation of acetals with allyltrimethylsilane
  作者：Yutaka Nishiyama、Keiko Shimoura、Noboru Sonoda

  DOI：10.1016/j.tetlet.2008.09.001

  日期：2008.11

  It was confirmed that the treatment of acetals with allyltrimethylsilane in the presence of a catalytic amount of the rhenium complex, ReBr(CO)(5), gave the corresponding homoallylic ethers in excellent to good yields. (C) 2008 Elsevier Ltd. All rights reserved.