4-(1,2,3,4,5,6,7,8-octahydro-[9]phenanthryl)-4-oxo-butyric acid | 337912-25-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 4-(1,2,3,4,5,6,7,8-octahydro-[9]phenanthryl)-4-oxo-butyric acid
• 英文别名: 4-(1,2,3,4,5,6,7,8-Octahydro-[9]phenanthryl)-4-oxo-buttersaeure；β-9-<1.2.3.4.5.6.7.8-Octahydro-phenanthroyl>-propionsaeure
• CAS: 337912-25-1
• 化学式: C₁₈H₂₂O₃
• 分子量: 286.371
• InChiKey: BPJVDUZNNCIXCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.49
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  54.37
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  4-(1,2,3,4,5,6,7,8-octahydro-[9]phenanthryl)-4-oxo-butyric acid 在 盐酸 、 氢氟酸 、 锌 作用下， 以 溶剂黄146 、 xylene 为溶剂， 生成 1,1'-Di-(3,4,5,6,7,8,9,10,11,12-octahydro-triphenylenyl)
  参考文献：
  名称：

  Benzologues of perylene, coronene and anthanthrene

  摘要：

  DOI：

  10.1016/s0040-4020(01)98612-0
• 作为产物：
  描述：

  三氯化铝 、 4-(1,2,3,4,5,6,7,8-octahydro-[9]anthryl)-4-oxo-butyric acid 生成 4-(1,2,3,4,5,6,7,8-octahydro-[9]phenanthryl)-4-oxo-butyric acid
  参考文献：
  名称：

  434.芳香族酮和酮酸的制备和异构化

  摘要：

  DOI：

  10.1039/jr9530002120

文献信息

• Personality disorders and psychoses form two distinct subgroups of homicide among female offenders
  作者：Hanna Putkonen、Jutta Collander、Marja-Liisa Honkasalo、Jouko Lönnqvist

  DOI：10.1080/09585180122116

  日期：2001.1

  This study examined circumstances of homicide by women in relation to their subsequent diagnoses. We investigated the written reports of forensic psychiatric examinations on 125 Finnish women who committed murder, attempted murder, manslaughter, or attempted manslaughter during 1982-92. In 86% of the cases the victims were adults, in 15% children. Intimate partners were the victims in 54% of the cases. Stabbing was the most frequent method and a quarrel the most frequent motive. The diagnoses of personality disorders and psychoses formed distinct subgroups. Psychotic women attacked proportionally more children than the personality disordered, who mainly attacked adults. Personality disordered women were more likely to have been intoxicated with alcohol at the time. Future treatment programmes and studies are suggested.
• 437. Isomerisation reactions. Part II
  作者：G. M. Badger、W. Carruthers、J. W. Cook

  DOI：10.1039/jr9490002044

  日期：——