| 478038-85-6

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• CAS: 478038-85-6
• 化学式: C₁₇H₂₆Ge
• 分子量: 302.983
• InChiKey: FQBCAEGBIXMJEI-MRXNPFEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.64
• 重原子数：
  18.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  正丁基锂 、 以 乙醚 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Niobium, titanium, zirconium and hafnium complexes incorporating germanium bridged ansa ligands. X-Ray crystal structures of [Zr{Me2Ge(η5-C5Me4)2}Cl2] and [M{Me2Ge(η5-C5Me4)(η5-C5H4)}Cl2] (M=Zr, Hf)

  摘要：

  Both the symmetric and asymmetric ansa-ligand precursors Me2Ge(C5Me4H)(2) (1) and Me2Ge(C5Me4H)(C5H4R) (R = H (3), Me (4)) and their lithium derivatives Li-2{Me2Ge(C5Me4)(2)} (5) and Li-2{Me2Ge(C5Me4)(C5H3R)} (R = H (6), Me (7)) have been prepared. The ansa-niobocene imido complex [Nb(=NBu'){Me2Ge(eta(5)-C5Me4)(eta(5)-C5H4)}Cl] (8) was synthesized by the reaction of [Nb(=NBu')Cl-3(py)(2)] with the appropriate lithiated ansa-precursor. The Group 4 metal complexes containing germanium bridged ansa-ligands [M{Me2Ge(eta(5)-C5Me4)(2)}Cl-2] (M = Ti (9), Zr (10), Hf (11)), [M{Me2Ge(eta(5)-C5Me4)(eta(5)-C5H4)}Cl-2] (M = Ti (12), Zr (13), Hf (14)), and [M{Me2Ge(eta(5)-C5Me4)(eta(5)-C5H3Me)}Cl-2] (M = Ti (15), Zr (16), Hf (17)) were prepared by the reaction of MCl4 and the corresponding lithiated ansa-derivative. The molecular structures of 10, 13 and 14 were determined by single-crystal X-ray diffraction studies. Preliminary results for the catalytic activity of the Group 4 ansa-metallocene complexes in the polymerization of ethylene and propylene are reported. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01576-0
• 作为产物：
  描述：

  四甲基环戊二烯锂 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Niobium, titanium, zirconium and hafnium complexes incorporating germanium bridged ansa ligands. X-Ray crystal structures of [Zr{Me2Ge(η5-C5Me4)2}Cl2] and [M{Me2Ge(η5-C5Me4)(η5-C5H4)}Cl2] (M=Zr, Hf)

  摘要：

  Both the symmetric and asymmetric ansa-ligand precursors Me2Ge(C5Me4H)(2) (1) and Me2Ge(C5Me4H)(C5H4R) (R = H (3), Me (4)) and their lithium derivatives Li-2{Me2Ge(C5Me4)(2)} (5) and Li-2{Me2Ge(C5Me4)(C5H3R)} (R = H (6), Me (7)) have been prepared. The ansa-niobocene imido complex [Nb(=NBu'){Me2Ge(eta(5)-C5Me4)(eta(5)-C5H4)}Cl] (8) was synthesized by the reaction of [Nb(=NBu')Cl-3(py)(2)] with the appropriate lithiated ansa-precursor. The Group 4 metal complexes containing germanium bridged ansa-ligands [M{Me2Ge(eta(5)-C5Me4)(2)}Cl-2] (M = Ti (9), Zr (10), Hf (11)), [M{Me2Ge(eta(5)-C5Me4)(eta(5)-C5H4)}Cl-2] (M = Ti (12), Zr (13), Hf (14)), and [M{Me2Ge(eta(5)-C5Me4)(eta(5)-C5H3Me)}Cl-2] (M = Ti (15), Zr (16), Hf (17)) were prepared by the reaction of MCl4 and the corresponding lithiated ansa-derivative. The molecular structures of 10, 13 and 14 were determined by single-crystal X-ray diffraction studies. Preliminary results for the catalytic activity of the Group 4 ansa-metallocene complexes in the polymerization of ethylene and propylene are reported. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01576-0