2,3,5-triphenyl-pent-4-yne-2,3-diol | 848830-11-5

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 2,3,5-triphenyl-pent-4-yne-2,3-diol
• 英文别名: Opt.-inakt. 3,4-Dihydroxy-1,3,4-triphenyl-pentin-(1)；2,3,5-Triphenyl-pent-4-in-2,3-diol
• CAS: 848830-11-5
• 化学式: C₂₃H₂₀O₂
• 分子量: 328.411
• InChiKey: AYPAWSLNKARQKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.83
• 重原子数：
  25.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  40.46
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2,3,5-triphenyl-pent-4-yne-2,3-diol 在 硫酸 作用下， 生成 5-Methyl-2,4,5-triphenyl-2,5-dihydro-furan-2-ol
  参考文献：
  名称：

  Social rank, shame and anger in primary and secondary psychopaths

  摘要：

  This study compared primary and secondary psychopaths (Blackburn, 1975 and Blackburn, 1998) in their perceptions of social rank, internal shame, angriness and intensity of anger in response to provocation. Fifty male mentally disordered offenders with the legal classification 'psychopathic disorder' were randomly sampled from a high-security (Special) hospital population and at interview a set of questionnaires was administered to each. Primary psychopaths perceived themselves to be significantly higher in social rank than secondary psychopaths, lower in shame, and lower in ratings of angriness, self-blame and anger towards others. A significant association was found between social rank and anger in response to provocation and an inverse relationship between Social rank and both shame and angriness. Regression analyses revealed that social rank and self-esteem best predicted variance in anger intensity to provocation, controlling for antisocial personality deviation. Primary and secondary psychopaths differed significantly, therefore, in their self-evaluative and social evaluative processes. The key differences lay in social rank evaluations and shame. Primary psychopaths assume dominance and threaten others who challenge them, while secondary psychopaths assume defensive, subordinate positions within a psychopathy hierarchy, seek dominance, but are sensitive to attacks from above and below. Findings provide preliminary support for an evolutionary perspective oil the role of social hierarchies in psychopathic behaviour.

  DOI：

  10.1080/09585180110056867
• 作为产物：
  描述：

  magnesium,ethynylbenzene,bromide 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙醚 作用下， 生成 2,3,5-triphenyl-pent-4-yne-2,3-diol
  参考文献：
  名称：

  Social rank, shame and anger in primary and secondary psychopaths

  摘要：

  This study compared primary and secondary psychopaths (Blackburn, 1975 and Blackburn, 1998) in their perceptions of social rank, internal shame, angriness and intensity of anger in response to provocation. Fifty male mentally disordered offenders with the legal classification 'psychopathic disorder' were randomly sampled from a high-security (Special) hospital population and at interview a set of questionnaires was administered to each. Primary psychopaths perceived themselves to be significantly higher in social rank than secondary psychopaths, lower in shame, and lower in ratings of angriness, self-blame and anger towards others. A significant association was found between social rank and anger in response to provocation and an inverse relationship between Social rank and both shame and angriness. Regression analyses revealed that social rank and self-esteem best predicted variance in anger intensity to provocation, controlling for antisocial personality deviation. Primary and secondary psychopaths differed significantly, therefore, in their self-evaluative and social evaluative processes. The key differences lay in social rank evaluations and shame. Primary psychopaths assume dominance and threaten others who challenge them, while secondary psychopaths assume defensive, subordinate positions within a psychopathy hierarchy, seek dominance, but are sensitive to attacks from above and below. Findings provide preliminary support for an evolutionary perspective oil the role of social hierarchies in psychopathic behaviour.

  DOI：

  10.1080/09585180110056867