| 888015-01-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 888015-01-8
• 化学式: C₄₄H₅₁N₁₁OZn
• 分子量: 815.352
• InChiKey: ATBTWKJSSAKPDX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  喹醛酰氯 、 在 C₅H₅N 作用下， 以 吡啶 为溶剂， 生成 [7,8,12,13,17,18-hexapropyl-2,3-di-(quinoline-2-carboxamido)porphyrazinato]zinc(II)
  参考文献：
  名称：

  Porphyrazines as Molecular Scaffolds:  Flexible Syntheses of Novel Multimetallic Complexes

  摘要：

  Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.

  DOI：

  10.1021/ic060176n
• 作为产物：
  描述：

  7,8,12,13,17,18-hexapropyl-[1,2,5]selenadiazolo[3,4-q]porphyrazine 在 (CH₃)2NCHO 、 H₂S 、 C₅H₅N 作用下， 以 吡啶 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Porphyrazines as Molecular Scaffolds:  Flexible Syntheses of Novel Multimetallic Complexes

  摘要：

  Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.

  DOI：

  10.1021/ic060176n