Carbon monoxide;hydrofluoride | 104505-49-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Carbon monoxide;hydrofluoride
• CAS: 104505-49-9
• 化学式: CO*FH
• 分子量: 48.0167
• InChiKey: QGGYSAJKSPQZHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Carbon monoxide;hydrofluoride 、 Phosphoric Acid Dipotassium 以40%的产率得到
  参考文献：
  名称：

  JIANG, ZONGHUI;CHALABI, PHILLIP;MERTES, KRISTIN BOWMAN;JAHANSOUZ, HOSSAIN+, BIOORG. CHEM., 17,(1989) N, C. 313-329

  摘要：

  DOI：
• 作为产物：
  描述：

  一氧化碳 、 氢氟酸 以 solid matrix 为溶剂， 生成 Carbon monoxide;hydrofluoride
  参考文献：
  名称：

  弱配合物的两种结构排列的基质俘获

  摘要：

  DOI：

  10.1021/j100312a020

文献信息

• FTIR spectra of base -- HF complexes in noble gas matrices
  作者：Lester Andrews

  DOI：10.1016/0022-2860(88)80046-2

  日期：1988.1

  Abstract FTIR matrix isolation studies can provide a wealth of new information on base--HF complexes. In particular, complexes that are difficult to prepare, such as NH 2 F--HF, NH 2 CN--HF and O 3 --HF can be observed in solid matrices. Very weak complexes like H 2 --HF and O 2 --HF require solid neon to minimize matrix effects. Finally, less stable structural arrangements such as CO--HF can be identified

  摘要 FTIR 基质分离研究可以提供大量关于碱-HF 配合物的新信息。特别是难于制备的配合物，如NH 2 F--HF、NH 2 CN--HF和O 3 -HF可以在固体基质中观察到。非常弱的配合物，如 H 2 --HF 和 O 2 --HF 需要固体氖以尽量减少基质效应。最后，稳定性较差的结构排列，如 CO-HF，可以在与更稳定的 OC-HF 复合物的同一矩阵中识别。
• The rotational spectra of weakly bound dimers of carbon monoxide and the hydrogen halides HX (X=F, Cl, and Br)
  作者：A. C. Legon、P. D. Soper、M. R. Keenan、T. K. Minton、T. J. Balle、W. H. Flygare

  DOI：10.1063/1.439859

  日期：1980.7

  A microwave spectrometer was used to measure the molecular constants of the dimers and to establish the linearity of the atom arrangement. (AIP)
• The rotational spectrum, H, ¹⁹F nuclear spin–nuclear spin coupling, D nuclear quadrupole coupling, and molecular geometry of a weakly bound dimer of carbon monoxide and hydrogen fluoride
  作者：A. C. Legon、P. D. Soper、W. H. Flygare

  DOI：10.1063/1.441747

  日期：1981.5

  A dimer formed between carbon monoxide and hydrogen fluoride has been detected and identified in the gas phase through its rotational spectrum by using a pulsed Fourier transform microwave spectrometer equipped with a pulsed nozzle source of the dimers and a Fabry-Perot cavity. Rotational constants B0, centrifugal distortion constants DJ, deuterium nuclear quadrupole coupling constants χD, and the nuclear spin–nuclear spin coupling constants SHF and SDF for the vibrational ground state of each of the five isotopic species investigated are as follows (the errors in B0 and DJ are discussed in the text):                             These spectroscopic constants have been interpreted in terms of a linear equilbrium geometry in which the atoms are in the order OC⋅⋅⋅HF and in which the weak binding is therefore through a hydrogen bond to the carbon atom. Various quantities characterizing the intermolecular interaction potential have also been estimated from the above constants and are used with those similarly determined to make comparison both within the series OC⋅⋅⋅HX (X = F, Cl, and Br) and among the different series B⋅⋅⋅HX (B = Ar, Kr, OC; X = F, Cl, and Br).