[Ru(,4′-dinonyl-2,2′-bipyridine)(2,2′-bipyridine-4,4′-diphosphonic acid)Cl2] | 1567918-57-3

• 英文名称: [Ru(,4′-dinonyl-2,2′-bipyridine)(2,2′-bipyridine-4,4′-diphosphonic acid)Cl2]
• 英文别名: [Ru(dnbpy)(dpbpy)Cl₂] 4；[Ru(,4′-dinonyl-2,2′-bipyridine)(2,2′-bipyridine-4,4′-diphosphonic acid)Cl₂]
• CAS: 1567918-57-3
• 化学式: C₃₈H₅₄Cl₂N₄O₆P₂Ru
• 分子量: 896.793
• InChiKey: LCYSNJJKRJFDDH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(η6-p-cymene)Ru(4,4'-di-n-nonyl bipyridine)Cl] 、 2,2'-联吡啶-4,4'-二基二(膦酸) 反应 4.0h， 以40 mg的产率得到[Ru(,4′-dinonyl-2,2′-bipyridine)(2,2′-bipyridine-4,4′-diphosphonic acid)Cl2]
  参考文献：
  名称：

  Phosphonic acid anchored ruthenium complexes for ZnO-based dye-sensitized solar cells

  摘要：

  We report on the development of ruthenium dyes for the application in flexible ZnO based dyesensitized solar cells. The ZnO based solar cells were prepared by electrodeposition using eosin Y as a structure-directing agent. The newly synthesized ruthenium dyes differed in the complexity of the extended pi-donor-system and in their anchor moieties. As alternatives to carboxylic acids as anchor groups, dyes carrying phosphonic acids were studied. Comparison of the dyes contrary to what could be expected showed that the phosphonic acid anchored dyes were not superior to the carboxylic anchored dyes. A surprising second effect was that the dyes with the least sophisticated ligands performed best. Exploring possible reasons we established a simple model that allows pre-evaluation of the applicability of the dyes before testing them in real solar cells. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.12.018