| 1451075-61-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• CAS: 1451075-61-8
• 化学式: C₅₉H₃₉N₅O₂Zn
• 分子量: 915.381
• InChiKey: QFKXMZZWRHEJLH-BYTXNLINSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 三氟乙酸 作用下， 以 氯仿 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  New flavonoid–porphyrin conjugates via Buchwald–Hartwig amination: synthesis and photophysical studies

  摘要：

  New flavonoid-porphyrin conjugates were synthesized using the cross-coupling Buchwald-Hartwig amination for the coupling of flavonoid and porphyrin moieties. A unique di-substituted flavone-porphyrin conjugate was also synthesized under similar reaction conditions for the first time. All the conjugates were fully characterized by NMR spectroscopy. The photophysical properties namely fluorescence and singlet oxygen production were evaluated considering their use for photodynamic therapy applications. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.07.089
• 作为产物：
  描述：

  5-(4-aminophenyl)-10,15,20-triphenyl-porphyrinato zinc(II) 、 4-bromo-2'-hydroxylchalcone 在 potassium tert-butylate 、 palladium diacetate 、 R-(+)-1,1'-联萘-2,2'-双二苯膦 作用下， 以 甲苯 为溶剂， 以31%的产率得到
  参考文献：
  名称：

  New flavonoid–porphyrin conjugates via Buchwald–Hartwig amination: synthesis and photophysical studies

  摘要：

  New flavonoid-porphyrin conjugates were synthesized using the cross-coupling Buchwald-Hartwig amination for the coupling of flavonoid and porphyrin moieties. A unique di-substituted flavone-porphyrin conjugate was also synthesized under similar reaction conditions for the first time. All the conjugates were fully characterized by NMR spectroscopy. The photophysical properties namely fluorescence and singlet oxygen production were evaluated considering their use for photodynamic therapy applications. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.07.089