| 1284175-82-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• CAS: 1284175-82-1
• 化学式: C₁₆H₁₅NOS
• 分子量: 269.367
• InChiKey: QBKCFRHWQLGEBS-VBKFSLOCSA-N

反应信息

• 作为产物：
  描述：

  3-phenyl-1-(pyridin-4-yl)prop-2-yn-1-one 、 乙硫醇 在 三丁基膦 作用下， 以 二氯甲烷 为溶剂， 反应 0.17h， 生成 、
  参考文献：
  名称：

  Tributylphosphine-catalyzed reaction of ethanethiol with alkynyl ketones

  摘要：

  A stereoselective and effective method for the synthesis of vinyl thioethers has been developed. This method is based on the Michael addition of ethanethiol to various alkynyl ketones using 10 mol% of tributylphosphine as catalyst. Most of alkynyl ketones react with ethanethiol in this system to yield mainly Z-isomer of vinyl thioether adducts, only in one case mainly E-isomer of vinyl thioether adducts was observed. (C) 2010 Qing Fa Zhou. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2010.11.007