6-Methyl-6-vinyl-fulven | 7301-20-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 6-Methyl-6-vinyl-fulven
• 英文别名: 6-Vinylfulfen；6-methyl-6-vinylfulvene；5-But-3-en-2-ylidenecyclopenta-1,3-diene
• CAS: 7301-20-4
• 化学式: C₉H₁₀
• 分子量: 118.178
• InChiKey: GXKWDMRZALAAIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  6-Methyl-6-vinyl-fulven 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 以40%的产率得到2-(but-3-en-2-ylidene)cyclopent-3-enone
  参考文献：
  名称：

  An exceptionally simple and efficient synthesis of 6-methyl-6-vinylfulvene, and its oxidative transformations

  摘要：

  A new efficient synthesis of 6-methyl-6-vinylfulvene was developed, starting from the 6-(2-hydroxyethyl)-6-methylfulvene. With larger quantities of the title compound in hand, its photooxygenation with singlet oxygen Was Studied. Cyclization of the cyclopropanone intermediate to both vinyl moieties in the unsaturated system was observed, whereas the saturated endoperoxide gave mostly the cyclopentenone derivative. m-CPBA attacks exclusively the endocyclic double bonds and gives the 3 -cyclopentenones via the unstable epoxides. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.02.221
• 作为产物：
  描述：

  3-Cyclopenta-2,4-dien-1-ylidenebutyl methanesulfonate 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 二氯甲烷 为溶剂， 生成 6-Methyl-6-vinyl-fulven
  参考文献：
  名称：

  An exceptionally simple and efficient synthesis of 6-methyl-6-vinylfulvene, and its oxidative transformations

  摘要：

  A new efficient synthesis of 6-methyl-6-vinylfulvene was developed, starting from the 6-(2-hydroxyethyl)-6-methylfulvene. With larger quantities of the title compound in hand, its photooxygenation with singlet oxygen Was Studied. Cyclization of the cyclopropanone intermediate to both vinyl moieties in the unsaturated system was observed, whereas the saturated endoperoxide gave mostly the cyclopentenone derivative. m-CPBA attacks exclusively the endocyclic double bonds and gives the 3 -cyclopentenones via the unstable epoxides. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.02.221