1,2-bis-[(γ-gem-dichlorocyclopropylmethyloxy)propylthio]ethane | 918826-56-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,2-bis-[(γ-gem-dichlorocyclopropylmethyloxy)propylthio]ethane
• 英文别名: 1,14-Bis(2,2-dichlorocyclopropyl)-2,13-dioxa-6,9-dithiatetradecane；1,1-dichloro-2-[3-[2-[3-[(2,2-dichlorocyclopropyl)methoxy]propylsulfanyl]ethylsulfanyl]propoxymethyl]cyclopropane
• CAS: 918826-56-9
• 化学式: C₁₆H₂₆Cl₄O₂S₂
• 分子量: 456.325
• InChiKey: JBLFXPPWOFSIBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  24
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  69.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,2-乙二硫醇 、 2-(allyloxymethyl)-1,1-dichlorocyclopropane 在 偶氮二异丁腈 作用下， 以87%的产率得到1,2-bis-[(γ-gem-dichlorocyclopropylmethyloxy)propylthio]ethane
  参考文献：
  名称：

  Chlorocyclopropane-containing sulfides as additives for lubricating oils

  摘要：

  Chlorocyclopropane-containing sulfides were synthesized via the radical-initiated reaction of thiophenol and ethanedithiol with vinyl(allyl)-gem-dichlorocyclopropyl ethers and characterized. The antiwear and extreme-pressure properties of the synthesized adducts were studied, and these compounds were shown to be effective additives for lubricating oils.

  DOI：

  10.1134/s0965544106030121

文献信息

• Chlorocyclopropane-containing sulfides as additives for lubricating oils
  作者：R. Z. Shakhnazarli、S. S. Gasanova、A. M. Guliev

  DOI：10.1134/s0965544106030121

  日期：2006.5

  Chlorocyclopropane-containing sulfides were synthesized via the radical-initiated reaction of thiophenol and ethanedithiol with vinyl(allyl)-gem-dichlorocyclopropyl ethers and characterized. The antiwear and extreme-pressure properties of the synthesized adducts were studied, and these compounds were shown to be effective additives for lubricating oils.