(6-Chloro-2-methylhept-6-en-3-yn-2-yl) acetate | 332113-31-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (6-Chloro-2-methylhept-6-en-3-yn-2-yl) acetate
• CAS: 332113-31-2
• 化学式: C₁₀H₁₃ClO₂
• 分子量: 200.665
• InChiKey: FGSVNNXDKDBVGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  三溴甲烷 、 (6-Chloro-2-methylhept-6-en-3-yn-2-yl) acetate 在 苄基三乙基氯化铵 sodium hydroxide 作用下， 反应 1.0h， 以24.4%的产率得到[5-(2,2-dibromo-1-chlorocyclopropyl)-2-methylpent-3-yn-2-yl] acetate
  参考文献：
  名称：

  Veliev; Chalabieva; Shatirova, Russian Journal of Organic Chemistry, 2000, vol. 36, # 7, p. 960 - 964

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸酐 、 6-chloro-2-methylhepta-6-en-3-yn-2-ol 在 硫酸 作用下， 以70.1%的产率得到(6-Chloro-2-methylhept-6-en-3-yn-2-yl) acetate
  参考文献：
  名称：

  Allylacetylenes and their derivatives as inhibitors of steel corrosion in sulfuric acid

  摘要：

  New functionalized derivatives of allylacetylenes were prepared, and their ability to inhibit corrosion of St.3 low-carbon steel in 5 N sulfuric acid was studied. The effectiveness of inhibition of steel corrosion was studied in relation to the structure of acetylene derivatives, their concentration, and temperature of acidic medium.

  DOI：

  10.1134/s1070427206110176

文献信息

• Allylacetylenes and their derivatives as inhibitors of steel corrosion in sulfuric acid
  作者：M. G. Veliev、N. M. Agaev、M. I. Shatirova、A. Z. Chalabieva、G. D. Geidarova、S. S. Alieva

  DOI：10.1134/s1070427206110176

  日期：2006.11

  New functionalized derivatives of allylacetylenes were prepared, and their ability to inhibit corrosion of St.3 low-carbon steel in 5 N sulfuric acid was studied. The effectiveness of inhibition of steel corrosion was studied in relation to the structure of acetylene derivatives, their concentration, and temperature of acidic medium.
• Veliev; Chalabieva; Shatirova, Russian Journal of Organic Chemistry, 2000, vol. 36, # 7, p. 960 - 964
  作者：Veliev、Chalabieva、Shatirova、Gakhramanov

  DOI：——

  日期：——