4-nonyloxycinnamic acid | 111833-23-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: 4-nonyloxycinnamic acid
• 英文别名: (E)-4-Nonyloxycinnamic acid；4-nonyloxy-trans-cinnamic acid；4-Nonyloxy-trans-zimtsaeure；(E)-3-(4-nonoxyphenyl)prop-2-enoic acid
• CAS: 111833-23-9
• 化学式: C₁₈H₂₆O₃
• 分子量: 290.403
• InChiKey: ZHNANUXWOCUJGB-SDNWHVSQSA-N

物化性质

• 沸点：
  439.2±20.0 °C(Predicted)
• 密度：
  1.033±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  21
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-nonyloxycinnamic acid 、 (R)-4-(2-氯丙氧基)苯酚 在 4-吡咯烷基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 乙醚 为溶剂， 生成 (R)-4'-(2-chloropropoxy) 4-nonyloxycinnamate
  参考文献：
  名称：

  Alstermark, Christer; Nilsson, Martin; Otterholm, Bengt, Molecular Crystals and Liquid Crystals (1969-1991), 1987, vol. 150, p. 277 - 288

  摘要：

  DOI：
• 作为产物：
  描述：

  (E)-3-(4-Nonyloxy-phenyl)-acrylic acid methyl ester 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 生成 4-nonyloxycinnamic acid
  参考文献：
  名称：

  Non-Chiral Compounds Exhibiting Alternating Tilt Smectic Phases

  摘要：

  In this article we present an investigation of the liquid crystal properties of nonchiral and racemic branched alkyl chain (swallow-tailed) molecules and some chiral analogues based on a cinnamic acid core group, It was found in these systems that increasing the extent of the branching of the terminal alkyl chain increased the incidence of alternating tilt smectic phases, whereas smectic C-alpha and smectic C-gamma phases were suppressed. X-ray studies of the effect on the layer spacing in the smectic A phase of increasing the long alkyl branch of one series of compounds are included. Results of polarisation studies on some chiral analogues are also reported.

  DOI：

  10.1080/10587259508038683

文献信息

• Mesomorphism dependence on central bridge and tail ended polar group
  作者：Avani R. Ranchchh、Kavita Chavda、Roshani Bhanderi、Suman Patel、U. C. Bhoya

  DOI：10.1080/15421406.2018.1499595

  日期：2018.4.13

  A novel azoester homologous series of laterally and terminally substituted viz, RO-C6H4-CH=CH-COO-C6H3-(CH3) -N=N-C6H4-Cl is synthesized, characterized and studied with a view to understand and establish the relation between molecular structure and thermotropic liquid crystalline property of its homologs. Series consists of twelve homologs. LC properties commence from very first member of a series and continue up to last homolog as enantiotropic nematic with absence of smectic property even in the monotropic condition. Transition temperatures of homologs were determined by polarizing optical microscopy equipped with a heating stage. The transition curves Cr?N and N?I behaved in normal manner. Thermal stability for nematic is 196.7 degrees C whose mesophaselength ranges from 35 degrees C to 131 degrees C.
• Inui, S.; Suzuki, T.; Iimura, N., Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 1994, vol. 239, p. 1 - 10
  作者：Inui, S.、Suzuki, T.、Iimura, N.、Iwane, H.、Nohira, H.

  DOI：——

  日期：——
• US5037574A
  申请人：——

  公开号：US5037574A

  公开（公告）日：1991-08-06
• US5139696A
  申请人：——

  公开号：US5139696A

  公开（公告）日：1992-08-18
• Non-Chiral Compounds Exhibiting Alternating Tilt Smectic Phases
  作者：R. P. Tuffin、J. W. Goodby、D. Bennemann、G. Heppke、D. Lötzsch、G. Scherowsky

  DOI：10.1080/10587259508038683

  日期：1995.2

  In this article we present an investigation of the liquid crystal properties of nonchiral and racemic branched alkyl chain (swallow-tailed) molecules and some chiral analogues based on a cinnamic acid core group, It was found in these systems that increasing the extent of the branching of the terminal alkyl chain increased the incidence of alternating tilt smectic phases, whereas smectic C-alpha and smectic C-gamma phases were suppressed. X-ray studies of the effect on the layer spacing in the smectic A phase of increasing the long alkyl branch of one series of compounds are included. Results of polarisation studies on some chiral analogues are also reported.