| 186296-64-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• CAS: 186296-64-0
• 化学式: C₃₀H₄₆O₄Ti
• 分子量: 518.573
• InChiKey: LFQYPWXXOSZJIM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三甲基溴硅烷 、 以 not given 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Nine-Membered Titanacyclic Complexes Based on an Ethylene-Bridged Bis(phenolato) Ligand:  Synthesis, Structure, and Olefin Polymerization Activity

  摘要：

  Tetravalent titanium complexes containing the ethylene-linked bis(phenolato) ligand ebmp exhibit a C-2-symmetric conformation according to single-crystal X-ray structural analyses. In solution, a fluxional process equivalent to an enantiomerization is detected. Upon activation, with. methylaluminoxane, these complexes copolymerize ethylene and styrene with remarkably high incorporation of styrene.

  DOI：

  10.1021/om9704105
• 作为产物：
  描述：

  titanium(IV) isopropylate 、 2-叔丁基-6-[2-(3-叔丁基-2-羟基-5-甲基苯基)乙基]-4-甲基苯酚 以 正己烷 为溶剂， 以98%的产率得到
  参考文献：
  名称：

  Nine-Membered Titanacyclic Complexes Based on an Ethylene-Bridged Bis(phenolato) Ligand:  Synthesis, Structure, and Olefin Polymerization Activity

  摘要：

  Tetravalent titanium complexes containing the ethylene-linked bis(phenolato) ligand ebmp exhibit a C-2-symmetric conformation according to single-crystal X-ray structural analyses. In solution, a fluxional process equivalent to an enantiomerization is detected. Upon activation, with. methylaluminoxane, these complexes copolymerize ethylene and styrene with remarkably high incorporation of styrene.

  DOI：

  10.1021/om9704105