2,2'-O-β-D-fructopyranosyl glycerol | 224623-31-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2'-O-β-D-fructopyranosyl glycerol
• 英文别名: 2-O-β-D-fructofuranosylglycerol
• CAS: 224623-31-8
• 化学式: C₉H₁₈O₈
• 分子量: 254.237
• InChiKey: ACWWQNJAMOKJMO-LURQLKTLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.84
• 重原子数：
  17.0
• 可旋转键数：
  6.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  139.84
• 氢给体数：
  6.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  N,O-双三甲硅基乙酰胺 、 2,2'-O-β-D-fructopyranosyl glycerol 在 吡啶 作用下， 反应 1.0h， 生成
  参考文献：
  名称：

  Enzymatic Synthesis of Fructosyl Glycerol

  摘要：

  The enzymatic synthesis of beta 2-2' and beta 2-1'-D- fructopyranosyl glycerol was carried out with levansucrase from Bacillus circulans or B. subtilis, using sucrose as fructosyl donor and glycerol. The specificity and efficiency of the enzyme was modified by controlling both the water and the total substrate concentrations. The products were purified by HPLC and analyzed by (1)H, (13)C NMR and GC-MS.

  DOI：

  10.1080/07328309908543995
• 作为产物：
  描述：

  甘油 、 蔗糖 在 phosphate buffer 作用下， 以 水 为溶剂， 反应 40.0h， 以40%的产率得到2,1'-O-β-D-fructopyranosyl glycerol
  参考文献：
  名称：

  Enzymatic Synthesis of Fructosyl Glycerol

  摘要：

  The enzymatic synthesis of beta 2-2' and beta 2-1'-D- fructopyranosyl glycerol was carried out with levansucrase from Bacillus circulans or B. subtilis, using sucrose as fructosyl donor and glycerol. The specificity and efficiency of the enzyme was modified by controlling both the water and the total substrate concentrations. The products were purified by HPLC and analyzed by (1)H, (13)C NMR and GC-MS.

  DOI：

  10.1080/07328309908543995