| 1044286-21-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1044286-21-6
• 化学式: C₁₀₃H₁₁₀N₈O₂Zn
• 分子量: 1557.45
• InChiKey: GESXWYDEEZZRKW-KNGVBHAWSA-N

反应信息

• 作为产物：
  描述：

  在 zinc diacetate 作用下， 以 四氢呋喃 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  Highly Linear Self-Assembled Porphyrin Wires

  摘要：

  An efficient noncovalent assembly process involving high geometrical control was applied to a linear bis-(imidazolyl zinc porphyrin) 7Zn, bearing C-18 substitutents, to generate linear multiporphyrin wires. The association process is based on imidazole recognition within the cavity of the phenanthroline-strapped zinc porphyrin. In chlorinated solvents, discrete soluble oligomers were obtained after (7Zn)(n) was end-capped with a terminal single imidazolyl zinc porphyrin derivative 4Zn. These soluble species, as well as their destabilization in the presence of protic solvents, were studied by UV-visible and time-resolved luminescence. In the solid state, assemblies as long as 480 nm, which corresponds to 190 iterative units or a total of 380 porphyrins, were observed by atomic force microscopy measurements on mica. The length and linearity of the porphyrin wires obtained illustrate the potential of phenanthroline-strapped porphyrins for the directional control of self-assembly processes.

  DOI：

  10.1021/ic2001255