(Z)-1-phenylpent-1-en-3-one | 82782-06-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: (Z)-1-phenylpent-1-en-3-one
• CAS: 82782-06-7
• 化学式: C₁₁H₁₂O
• 分子量: 160.216
• InChiKey: LVGUHATVVHIJET-HJWRWDBZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (Z)-1-phenylpent-1-en-3-one 在 lithium perchlorate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以100%的产率得到methyl-2 (oxo-1-propyl)-4-diphenyl-3,5-cyclohexanone
  参考文献：
  名称：

  Oligomerisations electro-assistees —II

  摘要：

  DOI：

  10.1016/s0040-4020(01)91372-9
• 作为产物：
  描述：

  5-phenyl-3-ethyl-Δ²-isoxazoline 在 盐酸 、 四氢化物钛 、 碳酸氢钠 作用下， 以 甲醇 为溶剂， 反应 84.0h， 生成 (Z)-1-phenylpent-1-en-3-one
  参考文献：
  名称：

  Andersen, Soeren H.; Das, Nalin B.; Joergensen, Ruth D., Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1982, vol. 36, # 1, p. 1 - 14

  摘要：

  DOI：

文献信息

• Coveney, Donal J.; Patel, Vinod F.; Pattenden, Gerald, Journal of the Chemical Society. Perkin transactions I, 1990, # 10, p. 2721 - 2729
  作者：Coveney, Donal J.、Patel, Vinod F.、Pattenden, Gerald、Thompson, David M.

  DOI：——

  日期：——
• Cationic Rhodium(I)/BINAP Complex-Catalyzed Isomerization of Secondary Propargylic Alcohols to α,β-Enones
  作者：Ken Tanaka、Takeaki Shoji

  DOI：10.1021/ol051335u

  日期：2005.8.1

  We have developed a cationic rhodium(l)/BINAP complex-catalyzed isomerization of secondary propargylic alcohols to alpha,beta-enones. The asymmetric variant of this reaction, a kinetic resolution of secondary propargylic alcohols, was also developed with good selectivity. The mechanistic study revealed that the isomerization proceeds through intramolecular 1,3- and 1,2-hydrogen migration pathways.
• COVENEY, DONAL J.;PATEL, VINOD F.;PATTENDEN, GERALD;THOMPSON, DAVID M., J. CHEM. SOC. PERKIN TRANS. PT 1,(1990) N0, C. 2721-2728
  作者：COVENEY, DONAL J.、PATEL, VINOD F.、PATTENDEN, GERALD、THOMPSON, DAVID M.

  DOI：——

  日期：——
• LIQUID CRYSTAL ALIGNMENT AGENT, LIQUID CRYSTAL ALIGNMENT FILM, AND LIQUID CRYSTAL DISPLAY ELEMENT
  申请人：Chi Mei Corporation

  公开号：US20170022419A1

  公开（公告）日：2017-01-26

  A liquid crystal alignment agent capable of forming a liquid crystal alignment film having good pre-tilt angle light stability, the liquid crystal alignment film, and a liquid crystal display element having the liquid crystal alignment film are provided. The liquid crystal alignment agent includes a polymer (A), a photosensitive polysiloxane (B), and a solvent (C). The polymer (A) is obtained by reacting a mixture, wherein the mixture includes a tetracarboxylic dianhydride component (a1) and a diamine component (a2). The diamine component (a2) includes a diamine compound (a2-1) represented by formula (1). The photosensitive polysiloxane (B) is obtained by reacting a silane compound (b1-1) containing an epoxy group and a cinnamic acid derivative (b2).