[dicopper(I)(1,10-phenanthroline)2(4,4'-bisphenyl diphosphonate)] | 1262957-62-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [dicopper(I)(1,10-phenanthroline)2(4,4'-bisphenyl diphosphonate)]
• 英文别名: [Cu2(phen)2(C12H6(PO3H)2)]
• CAS: 1262957-62-9
• 化学式: C₃₆H₂₆Cu₂N₄O₆P₂
• 分子量: 799.665
• InChiKey: RCOKDVIEFPSSEG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 Cu(acac)₂ H₂O 、 [4-(4-膦酰苯基)苯基]膦酸 在 hydrofluoric acid 、 MoO₂ 作用下， 以 水 为溶剂， 以10%的产率得到[dicopper(I)(1,10-phenanthroline)2(4,4'-bisphenyl diphosphonate)]
  参考文献：
  名称：

  Metal-organodiphosphonates: Structural consequences of introducing aromatic tethering groups. The structures of [Cu(phen){HO3P(C12H8)PO3H}], [{Cu(phen)}2{HO3P(C12H8)PO3H}] and [Cu(terpy){HO3P(C12H8)PO3H}] and of the bimetallic materials [{Cu(LL)}2MoO2{HO3P(C12H8)PO3H}3] (LL=2,2-bipyridine, o-phenanthroline)

  摘要：

  Hydrothermal reactions were used to prepare three copper-organodiphosphonate compounds and two copper-molybdate-organodiphosphonate chains. Compound 1, [Cu(phen){HO3P(C12H8)PO3H}] is a binuclear Cu(II) compound, while [{Cu(phen)}(2){HO3P(C12H8)PO3H}] (2) is a Cu(I) species with distorted "T" shaped copper coordination geometry. In contrast, [Cu(terpy){HO3P(C12H8)PO3H}]center dot 1.5H(2)O (3.1.5H(2)O) exhibits a zig-zag chain structure. The isomorphous bimetallic diphosphonates, [{Cu(LL)}(2)MoO2 {HO3P(C12H8)PO3H}(3)]center dot H2O (LL = bpy (4.H2O), phen (5.H2O)) also exhibit chain structures, constructed from {Cu2MoO2} clusters, bridging aromatic diphosphonate ligands, and diphosphonates coordinating to the clusters at one terminus and projecting a second pendant terminus. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.07.030