2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}aniline | 1161412-19-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}aniline
• 英文别名: 2-[2-[2-(2-Methoxyethoxy)ethoxy]ethoxy]aniline
• CAS: 1161412-19-6
• 化学式: C₁₃H₂₁NO₄
• mdl: MFCD27090484
• 分子量: 255.314
• InChiKey: GZFUEYFXYHWOLU-UHFFFAOYSA-N

物化性质

• 沸点：
  384.7±32.0 °C(Predicted)
• 密度：
  1.091±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  18
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.538
• 拓扑面积：
  62.9
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}aniline 在 亚硝酸特丁酯 、 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 以84%的产率得到2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}benzenediazonium tetrafluoroborate
  参考文献：
  名称：

  Synthesis and Characterization of Diazonium Salts with Polyethylene Glycol Appendages and Resulting Films Afforded by Electrodeposition for Use as a Battery Separator Material

  摘要：

  The coating of three-dimensional nanostructured electrodes is a significant challenge for the future of many energy storage devices and, if successful, could profoundly increase battery power. The synthesis of a new class of monomers that can be electrochemically polymerized is a key first step in affording a conformally coated, nanoscale lithium-ion battery separator and is presented herein. Characterization of the monomers was accomplished via nuclear magnetic resonance and infrared spectroscopy. Planar films electrodeposited from the monomers were characterized using redox probe experiments and impedance spectroscopy. The films are chemically grafted to the underlying substrate (conformal, pinhole free, <10 nm thick) and exhibit electrical resistivity values as high as 28000 M Omega/cm.

  DOI：

  10.1021/cm501482h
• 作为产物：
  描述：

  对甲苯磺酸三缩乙二醇单甲醚酯 在 盐酸 、 palladium on activated charcoal 、 氢气 、 potassium carbonate 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 生成 2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}aniline
  参考文献：
  名称：

  Synthesis and Characterization of Diazonium Salts with Polyethylene Glycol Appendages and Resulting Films Afforded by Electrodeposition for Use as a Battery Separator Material

  摘要：

  The coating of three-dimensional nanostructured electrodes is a significant challenge for the future of many energy storage devices and, if successful, could profoundly increase battery power. The synthesis of a new class of monomers that can be electrochemically polymerized is a key first step in affording a conformally coated, nanoscale lithium-ion battery separator and is presented herein. Characterization of the monomers was accomplished via nuclear magnetic resonance and infrared spectroscopy. Planar films electrodeposited from the monomers were characterized using redox probe experiments and impedance spectroscopy. The films are chemically grafted to the underlying substrate (conformal, pinhole free, <10 nm thick) and exhibit electrical resistivity values as high as 28000 M Omega/cm.

  DOI：

  10.1021/cm501482h

文献信息

• Self-assembly, stability quantification, controlled molecular switching, and sensing properties of an anthracene-containing dynamic [2]rotaxane
  作者：Wing-Yan Wong、Ken Cham-Fai Leung、J. Fraser Stoddart

  DOI：10.1039/b926568f

  日期：——

  The rate of hydrolysis (t1/2 = 6.9 min) of the dynamic rotaxane in the presence of a small amount (1 equiv.) of acid was found to be very much faster than when the hydrolysis was carried out with a large amount (>100 equiv.) of water, when t1/2 > 140 min. Furthermore, it has been established that the anthracene fluorescence of the dynamic rotaxane rises with an increasing amount of acid. Two acid sensors

  通过在二胺和二醛之间进行模板自组装以形成[24] cro-8大环的新型含蒽的动态[2]轮烷的制备 二亚胺在含有仲二烷基铵离子中心作为模板的哑铃存在下，已被开发用于其感测特性。通过吸引蒽环系统（与哑铃相连的两个塞子之一）作为荧光探针的能力，对动态轮烷在平衡混合物中的荧光和荧光猝灭特性进行了研究和量化。外部刺激的存在，例如水，酸，盐和胺。由动态轮烷的水解所表示的稳定性已通过以下方法进行监测：（i）蒽荧光和（ii）1 H NMR光谱中信号的运动。发现在少量（1当量）酸存在下，动态轮烷的水解速率（t 1/2 = 6.9分钟）比大量水解时的水解速率快得多（t当量= 6.9分钟）（t 1/2 = 6.9分钟）。 > 100当量）水，当t 1/2 > 140分钟。此外，已经确定，动态轮烷的蒽荧光随着酸的增加而增加。已经识别出两种具有不同操作模式的酸传感器，即对数和线性。涉及不同投入的组合水，酸，盐和胺导