[(Ru(η4-1,5-cyclooctadiene))3(μ3-η6:η6:η6-triphenylene)] | 874998-90-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: [(Ru(η4-1,5-cyclooctadiene))3(μ3-η6:η6:η6-triphenylene)]
• 英文别名: (1Z,5Z)-cycloocta-1,5-diene;ruthenium;triphenylene
• CAS: 874998-90-0
• 化学式: C₄₂H₄₈Ru₃
• 分子量: 856.053
• InChiKey: ZTKBPWCBFLQJOA-NENTYLIWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  9,10-苯并菲 、 [(Ru(η4-1,5-cyclooctadiene))3(μ3-η6:η6:η6-triphenylene)] 以 乙腈 为溶剂， 生成 [Ru(η4-1,5-cyclooctadiene)(η6-triphenylene)] 、 [(Ru(η4-1,5-cyclooctadiene))2(μ2-η6:η6-triphenylene)]
  参考文献：
  名称：

  Synthesis of Mono-, Di-, and Triruthenium(0) Complexes Having a Triphenylene Ligand

  摘要：

  A series of mono-, di-, and triruthenium(0) complexes containing a triphenylene ligand, [Ru(eta(4)-1,5-COD)](n)(eta(6n)-triphenylene) (n = 1 (2), 2 (3), 3 (6)) have been prepared by the ligand exchange reaction of Ru(eta(4)-1,5-COD)(eta(6)-naphthalene) (1) with triphenylene, reduction of Ru(acac)(2)(eta(4)-1,5-COD) (4) with sodium/triphenylene, or hydrogenolysis of Ru(eta(4)-1,5-COD)(eta(6)-1,3,5-COT) (5) in the presence of triphenylene. These triphenylene complexes are interconvertible with each other by addition of a "Ru(eta(4)-1,5-COD)" fragment or free triphenylene.

  DOI：

  10.1021/om050875s
• 作为产物：
  描述：

  9,10-苯并菲 、 (η6-1,3,5-cyclooctatriene)(η4-1,5-cyclooctadiene)ruthenium(0) 、 氢气 以 四氢呋喃 为溶剂， 以16%的产率得到[(Ru(η4-1,5-cyclooctadiene))3(μ3-η6:η6:η6-triphenylene)]
  参考文献：
  名称：

  Synthesis of Mono-, Di-, and Triruthenium(0) Complexes Having a Triphenylene Ligand

  摘要：

  A series of mono-, di-, and triruthenium(0) complexes containing a triphenylene ligand, [Ru(eta(4)-1,5-COD)](n)(eta(6n)-triphenylene) (n = 1 (2), 2 (3), 3 (6)) have been prepared by the ligand exchange reaction of Ru(eta(4)-1,5-COD)(eta(6)-naphthalene) (1) with triphenylene, reduction of Ru(acac)(2)(eta(4)-1,5-COD) (4) with sodium/triphenylene, or hydrogenolysis of Ru(eta(4)-1,5-COD)(eta(6)-1,3,5-COT) (5) in the presence of triphenylene. These triphenylene complexes are interconvertible with each other by addition of a "Ru(eta(4)-1,5-COD)" fragment or free triphenylene.

  DOI：

  10.1021/om050875s