1,2-bis(4-((4-ethylphenyl)diazenyl)-2-((2-(methylthio)phenylimino)methyl)phenol)methylenbenzene | 1402168-09-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 1,2-bis(4-((4-ethylphenyl)diazenyl)-2-((2-(methylthio)phenylimino)methyl)phenol)methylenbenzene
• 英文别名: 4-[(4-Ethylphenyl)diazenyl]-2-[[2-[[2-[[2-[[5-[(4-ethylphenyl)diazenyl]-2-hydroxyphenyl]methylideneamino]phenyl]sulfanylmethyl]phenyl]methylsulfanyl]phenyl]iminomethyl]phenol
• CAS: 1402168-09-5
• 化学式: C₅₀H₄₄N₆O₂S₂
• 分子量: 825.07
• InChiKey: JHKVRCDGZZALAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  60
• 可旋转键数：
  16
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  165
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  1-(3-formyl-4-hydroxyphenylazo)-4-ethylbenzene 、 α,α'-bis(o-aminophenylthio)-1,2-xylene 以 乙醇 为溶剂， 反应 4.0h， 以90%的产率得到1,2-bis(4-((4-ethylphenyl)diazenyl)-2-((2-(methylthio)phenylimino)methyl)phenol)methylenbenzene
  参考文献：
  名称：

  Thermally stable water insoluble azo-azomethine dyes: Synthesis, characterization and solvatochromic properties

  摘要：

  Six new water insoluble azo-azomethine dyes have been synthesized via condensation reaction of alpha,alpha'-bis(o-aminophenylthio)-1,2-xylene with substituted azo-coupled salicylaldehyde. The condensation reaction provides the expected bis-iminated azo-azomethine dyes in good yields, ranging from 59% to 90%. The dyes have been characterized by IR. UV-Vis and H-1 NMR spectroscopic methods as well as elemental analysis. The thermal behavior of the prepared dyes has been determined using thermogravimetry technique. Furthermore, the effect of various organic solvents with different polarities on the UV-Vis spectra of the dyes has been also studied. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2012.07.013