(2-mercapto-3-phenyl-quinazolin-4(3H)-one)Cu(II)(ethylenediamine)(H2O)(thiocyanate) | 1259528-17-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: (2-mercapto-3-phenyl-quinazolin-4(3H)-one)Cu(II)(ethylenediamine)(H2O)(thiocyanate)
• CAS: 1259528-17-0
• 化学式: C₁₇H₁₉CuN₅O₂S₂
• 分子量: 453.048
• InChiKey: BMAYPXIFQNPCPQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 copper(II) nitrate trihydrate 、 3-苯基-2-硫代-2,3-二氢-4(1H)-喹唑啉酮 、 乙二胺 以 甲醇 为溶剂， 以76%的产率得到(2-mercapto-3-phenyl-quinazolin-4(3H)-one)Cu(II)(ethylenediamine)(H2O)(thiocyanate)
  参考文献：
  名称：

  Synthesis, Characterization, Thermal, and Electrochemical Properties of Co(II) and Cu(II) Pseudohalide Complexes with 2-mercapto-3-phenyl-quinazolin-4(3H)-one and ethylendiamine or 1,10-phenanthroline as Ligands

  摘要：

  Several complexes of the type [M(L)(en or phen)(H2O)X] (1a-4a and 1b-4b); where M = Co(II) and Cu(II); L = 2-mercapto-3-phenyl-quinazolin-4(3H)-one; en = ethylenediamine, phen = 1,10-phenanthroline; X = N-3 and NCS- have been prepared and characterized. The complex formation occurred through both nitrogen and sulphur atom of the ligand L. Electronic spectra and magnetic moment values suggest octahedral geometry for all complexes. The thermal behavior of the complexes revealed that the phen complexes are thermally more stable than the en complexes. The electrochemical behavior of the Cu(II) complexes showed that phen complexes appeared at more positive potential than corresponding en complexes.

  DOI：

  10.1080/15533174.2010.509296