Zn(N4C20H10-2,9-diphenyl-1,10-phenanthroline)(5,6-dimethyl-1H-benzimidazole) | 1144042-07-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Zn(N4C20H10-2,9-diphenyl-1,10-phenanthroline)(5,6-dimethyl-1H-benzimidazole)
• CAS: 1144042-07-8
• 化学式: C₆₅H₄₂N₈Zn
• 分子量: 1000.49
• InChiKey: RCMOCKVWTGETKU-NRXSGTAVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5,6-二甲基苯并咪唑 、 以 1,2-二氯乙烷 为溶剂， 生成 Zn(N4C20H10-2,9-diphenyl-1,10-phenanthroline)(5,6-dimethyl-1H-benzimidazole)
  参考文献：
  名称：

  Molecular Tools for the Self-Assembly of Bisporphyrin Photodyads: A Comprehensive Physicochemical and Photophysical Study

  摘要：

  Accessible and hindered phenanthroline-strapped Zn(II) porphyrin receptors exhibited suitable topography tailored to strongly and selectively bind N-1-unsubstituted imidazoles and imidazoles appended to free-base porphyrins. Distal binding was clearly driven by the formation of strong bifurcated hydrogen bonds with the phenanthroline unit of the receptors. An extensive physicochemical study emphasized the influence of bulkiness of the substrate and of the porphyrin receptor on the binding and self-assembly mechanism. Knowledge of the corresponding spectroscopic, thermodynamic, and kinetic data were of fundamental importance to elucidate and to model the photoinduced properties which occur within the self-assembled porphyrin dyads.

  DOI：

  10.1021/ic802407x