(2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrinato)zinc(II) | 63444-26-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrinato)zinc(II)
• 英文别名: zinc(II) 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin；Zn(2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin)；zinc β-octatethyl-meso-tetraphenylporphyrine；zinc(II) octaethyltetraphenylporphyrinate；Zn(5,10,15,20-tetraphenyloctaethylporphyrin-2H)；[Zn(Ph4octaethylporphyrinato)]
• CAS: 63444-26-8
• 化学式: C₆₀H₆₀N₄Zn
• 分子量: 902.553
• InChiKey: ABYBHHSTDWGYLF-KCVIGMLFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrinato)zinc(II) 在 溶剂黄146 作用下， 以 溶剂黄146 为溶剂， 生成 锌
  参考文献：
  名称：

  Dissociation kinetics of cobalt and zinc β-octabromo-meso-tetraphenyl- and β-octaethyl-meso-tetraphenylporphyrin complexes

  摘要：

  Kinetics of solvoprotolytic dissociation of zinc and cobalt porphyrin complexes with a porphyrin macrocycle distorted to different extents (beta-octaethyl-meso-tetraphenylporphyrin and beta-octabromo-meso-tetraphenylporphyrin) have been studied in binary proton-donating solvents. The main factor decreasing the stability of the porphyrin complexes is the distortion of the planar structure of the macrocycle. The reactivity of the cobalt porphyrins is governed by both structural and electronic effects.

  DOI：

  10.1134/s0023158407020024
• 作为产物：
  描述：

  2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin 在 zinc diacetate 、 sodium sulfate 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrinato)zinc(II)
  参考文献：
  名称：

  Synthesis and inversion barriers of undeca- and dodeca-substituted saddle shaped porphyrin complexes

  摘要：

  Synthesis and barriers to inversion of a series of highly saddle shaped complexes are reported. The Delta G(not equal) has decreased by 8 kJ mol(-1) at 243 K when the meso phenyl groups are replaced by bulkier 2,6-dichlorophenyl groups, and by 17 kJ mol(-1) when one of the peripheral ethyl groups is removed. (c) 2005 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2005.05.100

文献信息

• Electron transfer reaction of porphyrin and porphycene complexes of Cu(<scp>ii</scp>) and Zn(<scp>ii</scp>) in acetonitrile
  作者：Kaori Aoki、Toshimitsu Goshima、Yohei Kozuka、Yukiko Kawamori、Noboru Ono、Yoshio Hisaeda、Hideo D. Takagi、Masahiko Inamo

  DOI：10.1039/b812575a

  日期：——

  self-exchange rate constants between the parent porphyrin and porphycene complexes and their pi-cation radicals were determined using the Marcus cross relation for the electron transfer reaction. The obtained rate constants are in the order of 10(9) to 10(11) M(-1) s(-1) for the planar porphyrin and porphycene complexes and 10(4) to 10(6) M(-1) s(-1) for the nonplanar OETPP complexes at T = 25.0 degrees

  非平面2,3,7,8,12,13,17,18-八乙基-5,10,15,20-四苯基卟啉的Cu（II）和Zn（II）配合物的外球单电子氧化反应分光光度法研究了平面卟啉以及2,3,7,8,12,13,17,18-八乙基卟啉和5,10,15,20-四苯基卟啉的铜（2+）给出相应的pi-阳离子自由基在乙腈中。使用电子转移反应的马库斯（Marcus）交叉关系，确定了母卟啉与卟啉配合物及其pi-阳离子自由基之间的电子自交换速率常数。对于平面卟啉和卟啉配合物，所获得的速率常数约为10（9）至10（11）M（-1）s（-1），以及10（4）至10（6）M（-1） T = 25.0摄氏度时非平面OETPP配合物的s（-1）。
• The effect of chemical modification of the macrocycle on the complex formation between porphyrins and metal salts in organic solvents
  作者：O. V. Maltceva、N. Zh. Mamardashvili

  DOI：10.1134/s1070363217060123

  日期：2017.6

  The complex formation of β-octaethylporphyrin, β-octaethyl-meso-monophenylporphyrin, β-octaethyl-meso-tetraphenylporphyrin, meso-diphenylporphyrin, meso-triphenylporphyrin, and meso-tetraphenylporphyrin with Zn(II), Cu(II), Co(II), and Mn(II) acetates and chlorides in dimethylformamide, dimethylsulfoxide, pyridine, acetic acid, and a chloroform–methanol 1 : 1 mixture has been studied by means of spectrophotometry

  复合物的形成β-八乙基卟啉，β-octaethyl-的内消旋-monophenylporphyrin，β-octaethyl-内消旋-tetraphenylporphyrin，内消旋-diphenylporphyrin，内消旋-triphenylporphyrin和内消旋-四苯基卟啉用Zn（II），铜（II），钴（II ），通过分光光度法研究了二甲基甲酰胺，二甲基亚砜，吡啶，乙酸和氯仿-甲醇1：1混合物中的乙酸锰和氯化锰（II）。所观察到的规定与不同复杂性的卟啉中NH键的化学反应性概念一致。
• An Oxygen Paradox: Catalytic Use of Oxygen in Radical Photopolymerization
  作者：Liwen Zhang、Chenyu Wu、Kenward Jung、Yun Hau Ng、Cyrille Boyer

  DOI：10.1002/anie.201909014

  日期：2019.11.18

  or off, this system possesses the exciting capability of inducing temporal control by removal or reintroduction of oxygen. Furthermore, this multicomponent catalytic system was typified by controlled polymerizations of various acrylate and acrylamide monomers, which all resulted in well-defined polymers with low dispersity (<1.2). The process displayed excellent living characteristics that were demonstrated

  提出了一种特殊的自由基聚合反应，其中氧与三乙胺一起作为助催化剂，在锌存在下在PET-RAFT过程的远红光（690 nm，3 mW cm-2）中提供光活化。 II）（2,3,7,8,12,13,17,18-八乙基-5,10,15,20-四苯基卟啉）作为光催化剂。除了通过打开或关闭灯来施加时间控制的能力之外，该系统还具有通过去除或重新引入氧气来诱导时间控制的令人兴奋的能力。此外，该多组分催化体系的典型代表是各种丙烯酸酯和丙烯酰胺单体的受控聚合，所有这些聚合均导致定义明确的聚合物，且分散度低（<1.2）。
• Ema, Tadashi; Senge, Mathias O.; Nelson, Nora Y., Angewandte Chemie, 1994, vol. 106, # 18, p. 1951 - 1953
  作者：Ema, Tadashi、Senge, Mathias O.、Nelson, Nora Y.、Ogoshi, Hisanobu、Smith, Kevin M.

  DOI：——

  日期：——
• Pukhovskaya; Guseva; Semeikin, Russian Journal of Inorganic Chemistry, 2005, vol. 50, # 4, p. 572 - 576
  作者：Pukhovskaya、Guseva、Semeikin、Kuvshinova、Golubchikov

  DOI：——

  日期：——