[Cd2(8-[(pyridin-4-yl)methylthio]quinoline)2(NO3)4] | 1178907-66-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Cd2(8-[(pyridin-4-yl)methylthio]quinoline)2(NO3)4]
• 英文别名: Cadmium(2+); 8-(4-pyridylmethylsulfanyl)quinoline; tetranitrate；cadmium(2+);8-(pyridin-4-ylmethylsulfanyl)quinoline;tetranitrate
• CAS: 1178907-66-8
• 化学式: C₃₀H₂₄Cd₂N₈O₁₂S₂
• 分子量: 977.519
• InChiKey: LELAJJYHIGDUSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.88
• 重原子数：
  54
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  354
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  8-((pyridin-4-yl)methylthio)quinoline 、 cadmium(II) nitrate 以 甲醇 、 氯仿 为溶剂， 以43%的产率得到[Cd2(8-[(pyridin-4-yl)methylthio]quinoline)2(NO3)4]
  参考文献：
  名称：

  Syntheses, structures and bioactivities of cadmium(II) complexes with a tridentate heterocyclic N- and S-ligand

  摘要：

  Four cadmium(II) complexes of the semirigid tridentate ligand 8-[(pyridin-4-yl)methylthio]quinoline (TQMP4, L), namely, [CdL2](ClO4)(2) (1), [Cd(L)Br-2] (2), [Cd-2(L)(2)(NO3)(4)] (3), and [Cd-2(L)(2)I-4] (4), have been prepared by the methods of layering and the diffusing of diethyl ether. The structures of the complexes have been identified by elemental analysis (EA), infrared spectra (IR) and single-crystal diffraction. The different coordination modes of the ligands and counter anions result in a 2D (4, 4) net structure in complex 1, a 1D polymer chain in complex 2, and 0D binuclear rings in complexes 3 and 4. Their antibacterial and antifungal activities were also tested. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.03.041