2,2,5-trimethylundeca-3,4-diene | 1448195-57-0

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 2,2,5-trimethylundeca-3,4-diene
• CAS: 1448195-57-0
• 化学式: C₁₄H₂₆
• 分子量: 194.36
• InChiKey: GPTQWKUEEYEIRB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  14.0
• 可旋转键数：
  5.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  C₁₃H₂₄O 在 四甲基乙二胺 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 生成 2,2,5-trimethylundeca-3,4-diene
  参考文献：
  名称：

  Nitration of Silyl Allenes To Form Functionalized Nitroalkenes

  摘要：

  An efficient nitration of silyl allenes with nitrogen dioxide radical, generated from NaNO2 and AcOH, to form alpha-nitro-alpha,beta-unsaturated silyl oximes has been developed. A similar nitration could be achieved by using Fe(NO3)(3)center dot 9H(2)O and FeCl3 center dot 6H(2)O, but different from the regioselective oxime formation, two regioisomeric chloride-trapped products were isolated with varying ratios depending on the steric bulk of the silyl group. A novel ring-closure reaction of alpha-nitro-alpha,beta-unsaturated silyl oximes upon treating with TBAF to form isooxazolidinone derivatives was also developed.

  DOI：

  10.1021/ol401735v