ruthenium acetonitrile (2,2-dipyrazol-1-yl)propane tris(pyrid-2-yl)methoxymethane | 368857-49-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: ruthenium acetonitrile (2,2-dipyrazol-1-yl)propane tris(pyrid-2-yl)methoxymethane
• CAS: 368857-49-2
• 化学式: C₂₈H₃₀N₈ORu
• 分子量: 595.669
• InChiKey: BJJQZIUZJNPXOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ruthenium aqua (2,2-dipyrazol-1-yl)propane tris(pyrid-2-yl)methoxymethane 、 乙腈 以 硝酸 为溶剂， 生成 ruthenium acetonitrile (2,2-dipyrazol-1-yl)propane tris(pyrid-2-yl)methoxymethane 、 水
  参考文献：
  名称：

  Remarkable Rate Enhancement of Ligand Substitution Promoted by Geometrical Arrangement of Tridentate “Spectator” Ligands K.J.T. acknowledges Arco Chemical and the National Science Foundation for support of this research. M.H.V.H. gratefully acknowledges postdoctoral fellowship support from the Director's Office of Los Alamos National Laboratory. Los Alamos National Laboratory is operated by the University of California for the U.S. Department of Energy under Contract W-7405-ENG-36. M.H.V.H. also thanks Dr. Beverly K. Hartline (Deputy Laboratory Director, Argonne National Laboratory), Dr. Donald G. Lee (Chemistry Professor, University of Regina, Saskatchewan, Canada, S4S0A2), Dr. R. Thomas Baker (Los Alamos National Laboratory), and Dr. David E. Morris (Los Alamos National Laboratory) for their suggestions and discussions.

  摘要：

  DOI：

  10.1002/1521-3773(20011203)40:23<4469::aid-anie4469>3.0.co;2-3