heptakis[2,3-di-O-methyl-6-S-acetyl-6-thio]-β-cyclodextrin | 876953-33-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: heptakis[2,3-di-O-methyl-6-S-acetyl-6-thio]-β-cyclodextrin
• CAS: 876953-33-2
• 化学式: C₇₀H₁₁₂O₃₅S₇
• 分子量: 1738.1
• InChiKey: POGLKYAZDNQOSL-DCBUKTJTSA-N

反应信息

• 作为反应物：
  描述：

  heptakis[2,3-di-O-methyl-6-S-acetyl-6-thio]-β-cyclodextrin 在 sodium methylate 作用下， 以 甲醇 为溶剂， 反应 5.0h， 生成
  参考文献：
  名称：

  Synthesis of a Novel Class of Cyclodextrin-Based Nanotubes

  摘要：

  The synthesis and characterization of a novel class of structurally well-defined nanotubes from beta-cyclodextrin are described. These new hosts were formed using disulfide linkages that substitute all the primary hydroxyl groups of a beta-cyclodextrin. A deep and rigid hydrophobic channel with a size of more than 1.5 nm is found in the molecules. Because of their unique geometry and the potential biodegradability of the disulfide bond, this class of molecules could find broad applications in biology and other areas of research.

  DOI：

  10.1021/ol201065u
• 作为产物：
  描述：

  heptakis (6-O-methylsulfonyl-2,3-di-O-methyl)-β-cyclodextrin 、 potassium thioacetate 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 以56%的产率得到heptakis[2,3-di-O-methyl-6-S-acetyl-6-thio]-β-cyclodextrin
  参考文献：
  名称：

  Synthesis of a Novel Class of Cyclodextrin-Based Nanotubes

  摘要：

  The synthesis and characterization of a novel class of structurally well-defined nanotubes from beta-cyclodextrin are described. These new hosts were formed using disulfide linkages that substitute all the primary hydroxyl groups of a beta-cyclodextrin. A deep and rigid hydrophobic channel with a size of more than 1.5 nm is found in the molecules. Because of their unique geometry and the potential biodegradability of the disulfide bond, this class of molecules could find broad applications in biology and other areas of research.

  DOI：

  10.1021/ol201065u