| 1119275-90-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1119275-90-9
• 化学式: C₂₆H₃₈O₁₅S
• 分子量: 622.645
• InChiKey: IETVMDWPKDOGFU-YGZUFYSPSA-N

反应信息

• 作为反应物：
  描述：

  在 N-溴代丁二酰亚胺(NBS) 作用下， 以 二氯甲烷 、 水 、 丙酮 为溶剂， 反应 0.08h， 生成
  参考文献：
  名称：

  Synthesis of 2-deoxy-d-arabino/lyxo-hexopyranosyl disaccharides

  摘要：

  Synthesis of 2-deoxy-D-arabino/lyxo-hexopyranosyl disaccharides is reported. In these, the disaccharides contain 2-deoxy-arabino-hexopyranosyl and 2-deoxy-lyxo-hexopyranosyl sugars as either the reducing or the non-reducing or both the sugar units of the disaccharides. The activated 2-deoxy-1-thioglycosides served as the common precursors to prepare the 2-deoxy disaccharides with the above configurations. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2007.11.017
• 作为产物：
  描述：

  [(2R,3S,4R)-4-乙酰氧基-3-[(2R,3R,4S,5R,6R)-3,4,5-三乙酰氧基-6-(乙酰氧基甲基)四氢吡喃-2-基]氧基-3,4-二氢-2H-吡喃-2-基]甲基乙酸酯 、 乙硫醇 在 ammonium cerium(IV) nitrate 作用下， 以 乙腈 为溶剂， 反应 16.0h， 以66%的产率得到ethyl 4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-6-O-acetyl-2,3-dideoxy-1-thio-D-erythro-hex-2-enopyranoside
  参考文献：
  名称：

  Synthesis of 2-deoxy-d-arabino/lyxo-hexopyranosyl disaccharides

  摘要：

  Synthesis of 2-deoxy-D-arabino/lyxo-hexopyranosyl disaccharides is reported. In these, the disaccharides contain 2-deoxy-arabino-hexopyranosyl and 2-deoxy-lyxo-hexopyranosyl sugars as either the reducing or the non-reducing or both the sugar units of the disaccharides. The activated 2-deoxy-1-thioglycosides served as the common precursors to prepare the 2-deoxy disaccharides with the above configurations. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2007.11.017

文献信息

• Synthesis of 2-deoxy cyclic and linear oligosaccharides by oligomerization of monomers
  作者：Somak Paul、Srinivasarao Raghothama、Narayanaswamy Jayaraman

  DOI：10.1016/j.carres.2008.10.026

  日期：2009.1

  Cyclic and linear oligosaccharides constituted with 2-deoxy sugar units are synthesized by an oligomerization reaction involving activated thioglycoside monomers, consisting of a 2-deoxy sugar unit. The oligomerization promoter plays an important role in the formation of either the cyclic- or the linear oligosaccharides. Encapsulation abilities of a 2-deoxy cyclic hexamer with p-nitrophenot, by a H-1 NMR method, showed complexation of the guest molecule with the host molecule. (C) 2008 Elsevier Ltd. All rights reserved.