| 1609194-78-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1609194-78-6
• 化学式: C₅₈H₆₄Fe₂N₆O₁₂
• 分子量: 1148.87
• InChiKey: KOHGTPBGQCZKDG-HNLRKYIPSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-bis(allyloxy)-5,5'-di-tert-butyl-3,3'-methanediyldibenzenemathanol 在 manganese(IV) oxide 、 palladium 10% on activated carbon 、 对甲苯磺酸 、 三乙胺 作用下， 以 甲醇 、 乙腈 、 苯 为溶剂， 反应 50.5h， 生成
  参考文献：
  名称：

  Iron(III) and manganese(III) complexes of a pseudocalixarene tetraiminotetraphenol macrocyclic ligand: Structure, magnetism and electrochemistry

  摘要：

  The pseudocalixarene tetraiminotetraphenol macrocyclic ligand H4L has been structurally characterized and used to synthesize the complexes [(Fe2L)-L-III(NO3)(2)(H2O)(2)] (1), [(Fe2L)-L-III(Cl)(2)](infinity) (2), [{(Fe2L)-L-III(mu-O)}(2)]center dot 2CH(3)CN center dot H2O (3), [(Mn2L)-L-III(Cl)(2)]center dot 3H(2)O (4) and [(Mn2L)-L-III(OAc)(2)]center dot 5H(2)O (5). The crystal structures of 3 and 4 have been determined. Variable-temperature (2-295 K) magnetic susceptibility measurements have been carried out for 3 and the data have been fitted to the spin Hamiltonian H = -2JS(1).S-2 with J = -45 cm(-1). Cyclic voltammetric measurements carried out for 1 in N,N-dimethylformamide have revealed the presence of two reversible redox couples with E-1/2 = -180 and -280 mV, which coalesced into a single couple with E-1/2 = -220 mV with the addition of excess NaNO3. The two manganese(III) complexes undergo quasi-reversible reduction in methanol at the same potential with E-1/2 = -240 mV. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2014.03.011