[(1,10-phenanthroline) (homophthalate) cadmium(II)]n | 884492-75-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [(1,10-phenanthroline) (homophthalate) cadmium(II)]n
• 英文别名: [Cd(phen)(homophthalate)]n
• CAS: 884492-75-5
• 化学式: C₉H₆O₄*C₁₂H₈N₂*Cd
• 分子量: 470.763
• InChiKey: LEANGPNFZQRRIP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.12
• 重原子数：
  28.0
• 可旋转键数：
  3.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  106.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 邻羧基苯乙酸 、 cadmium(II) chloride 在 HCl 作用下， 以 乙醇 、 水 为溶剂， 以43%的产率得到[(1,10-phenanthroline) (homophthalate) cadmium(II)]n
  参考文献：
  名称：

  Four new cadmium(II) homophthalate diimine complexes: Syntheses, structures and fluorescence

  摘要：

  Four new complexes of homophthalate (hpht), [Cd(hpht)(phen)](n) (1), [Cd(hpht)(2,2'-bpy)](n) (2), [Cd(hpht)(2,2'-bpy)(H2O)](n) (.) 2nH(2)O (3), [Cd(hpht)(4,4'-bpy)](n) (.) nH(2)O (4), have been solvothermally synthesized and characterized. Both 1 and 2 are 1-D double-chains which are further extended to 2-D layer structure by the pi-pi interaction of phen (for 1) and 2,2'-bpy (for 2). Complex 3 is linear chain which is stacked to 3-D supramolecular network though the pi-pi interaction and hydrogen bonding. Complex 4 features a 2-D network formed by the linkages of bench-like chains though 4,4'-bpy. Both 1 and 2 exhibit intense blue fluorescence emission and 3 produces a green fluorescence, while 4 features a unique and very strong red fluorescence. Complexes 1-4 may be potential candidates for photoactive materials. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.042