8-methyltetracyclo<4.4.0.0^2,40^3,7>non-8-ene | 68902-59-0

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 8-methyltetracyclo<4.4.0.0^2,40^3,7>non-8-ene
• 英文别名: 8-methyltetracyclo[4.3.0.02,4.03,7]non-8-ene
• CAS: 68902-59-0
• 化学式: C₁₀H₁₂
• 分子量: 132.205
• InChiKey: PPQQMJGYLHXOMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 8-methyltetracyclo<4.4.0.0^2,40^3,7>non-8-ene 在 bis(acetylacetonato)palladium(II) 作用下， 生成 endo-8-methylpentacyclo<4.4.0^2,4.0^3,7.0^8,10>decane
  参考文献：
  名称：

  Reaction of diazoalkanes with unsaturated compounds. 11. Relative reactivity of olefins on catalytic cyclopropanation with diazomethane and palladium catalysts

  摘要：

  The relative reactivity of unsaturated compounds on catalytic cyclopropanation with diazomethane in the presence of catalysts based on Pd2+ [Pd(OAC)2, Pd(acac)2, (PPh3)2.PdCl2] has been studied using competing reactions. An interconnection was shown between the relative reactivity of the olefins and the coordinating activity of the C=C bond depending on its strain and spatial environment.

  DOI：

  10.1007/bf00863821