1-Decylidencyclopropan | 73726-89-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 1-Decylidencyclopropan
• 英文别名: Decylidenecyclopropane
• CAS: 73726-89-3
• 化学式: C₁₃H₂₄
• 分子量: 180.334
• InChiKey: ANSPRWIDTZZWQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-Decylidencyclopropan 、 对苯醌 以50%的产率得到
  参考文献：
  名称：

  Ciufolini Marco A., Rivera-Fortin M. Angelica, Zuzukin Vladimir, Whitmire+, J. Amer. Chem. Soc, 116 (1994) N 4, S 1272-1277

  摘要：

  DOI：
• 作为产物：
  描述：

  (1-Phenylseleno-1-cyclopropyl)-decan 生成 1-Decylidencyclopropan
  参考文献：
  名称：

  从硒化物制烯烃的新通用路线

  摘要：

  通过相应的硒盐上的碱反应，可以容易地从相应的硒化物制备包括亚烷基亚环丙烷的烯烃。该反应也适用于环丙基硫化物。

  DOI：

  10.1016/s0040-4039(01)86553-9

文献信息

• Metal Triflate–Catalyzed Se-Se Bond Cleavage and the Selective Additions Under Mild Conditions
  作者：Lei Yu、Lingfeng Ren、Rong Guo、Tian Chen

  DOI：10.1080/00397911.2010.494813

  日期：2011.7.1

  Abstract Metal triflate–catalyzed Se-Se bond cleavage would generate selenyl cations, which could add to activated C=C double bond selectively. The reaction conditions were mild and could be easily handled. The cleavage of Se-Se bond in this novel way under mild conditions might expand the view of organic synthesis and facilitate new synthetic strategies.

  摘要 金属三氟甲磺酸盐催化的 Se-Se 键断裂会产生硒基阳离子，硒基阳离子可以选择性地添加到活化的 C=C 双键上。反应条件温和，易于处理。在温和条件下以这种新方式裂解 Se-Se 键可能会扩展有机合成的视野并促进新的合成策略。
• Lewis Acid Catalyzed Reaction of Methylenecyclopropanes with 1,2-Diphenyldiselane or 1,2-Di-<i>p</i>-tolyldisulfane
  作者：Lei Yu、Jundong Meng、Ling Xia、Rong Guo

  DOI：10.1021/jo9006514

  日期：2009.7.17

  Catalyzed by Lewis acid, 1,2-diphenyldiselane or 1,2-di-p-tolyldisulfane could add to methylenecyclopropanes smoothly. Compared with the reported free radical additions, the results were quite different. A four-membered carbon ring was constructed to give cyclobutane-1,1-diylbis(phenylselane) derivatives or cyclobutane-1,1-diylbis(p-tolylsulfane) derivatives as products, which are useful intermediates in organic synthesis.
• Iron salt, a cheap, highly efficient and environment-friendly metal catalyst for Se–Se bond cleavage and the further reaction with methylenecyclopropanes under mild conditions
  作者：Lei Yu、Lingfeng Ren、Rong Yi、Yulan Wu、Tian Chen、Rong Guo

  DOI：10.1016/j.jorganchem.2010.11.047

  日期：2011.5

  FeCl3 was found to be a good catalyst in Se-Se bond cleavage. Further electrophilic additions to methylenecyclopropanes provide a convenient access to diphenylselenylcyclobutanes. Comparing with other Lewis acids, FeCl3 is much cheaper and the reaction conditions are milde and more tolerance to air and moisture. (C) 2010 Elsevier B.V. All rights reserved.
• Ciufolini, Marco A.; Rivera-Fortin, M. Angelica; Zuzukin, Vladimir, Journal of the American Chemical Society, 1994, vol. 116, # 4, p. 1272 - 1277
  作者：Ciufolini, Marco A.、Rivera-Fortin, M. Angelica、Zuzukin, Vladimir、Whitmire, Kenton H.

  DOI：——

  日期：——