diphenyl-bis(quinoline-2-carboxylato-κ² N,O)tin(IV) | 861908-58-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: diphenyl-bis(quinoline-2-carboxylato-κ² N,O)tin(IV)
• CAS: 861908-58-9
• 化学式: C₃₂H₂₂N₂O₄Sn
• 分子量: 617.248
• InChiKey: PFOHZQAIRPFPNQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  喹哪啶酸 、 双(三苯基锡)氧化物 以 苯 为溶剂， 以87.52%的产率得到diphenyl-bis(quinoline-2-carboxylato-κ² N,O)tin(IV)
  参考文献：
  名称：

  Synthesis and spectroscopic properties of diorganotin(IV) complexes of 2-quinaldate and crystal structures of (4-FC6H4CH2)2Sn(2-quin)2·2CH3CN and {[(2-ClC6H4CH2)2SnCl(2-quin)]2·CH3OH}n

  摘要：

  Twelve diorganotin(IV) complexes of 2-quinaldate R2Sn(2-quin)(2) and R2SnCl(2-quin) have been synthesized by dealkyltion reactions of 2-quinaldic acid (2-quinH) with (R3Sn)(2)O (R = PhCH2 1, 2-C/C6H4CH2 2, 2-FC6H4CH2 3, 4-FC6H4CH, 4,4-CNC6H4CH2 5, Ph 6, 2,4-Cl2C6H3CH2 7) and R3SnCl (R = 2-ClC6H4CH2 8, 4-C/C6H4CH2 9, 2-FC6H4CH2 10, 4-FC6H4CH2 11, PhCH2 12), and all the complexes have been characterized by elemental analysis, IR and multinuclear NMR (H-1, C-13, Sn-119) spectroscopies. The structures of (4-FC6H4CH2)(2)Sn(2-quin)(2)(.)2CH(3)CN (4) and {[(2-C/C6H4CH2)(2)Sn(2-quin)C l](2) (.) CH3OH}(n) (8) have been determined by X-ray diffraction. Studies show that complex 4 is a monomer with the central tin atom six-coordinated in a skew-trapezoidal-bipyramidal geometry and complex 8 is a one-dimensional polymer with the tin atom six-coordinated. Studies also show that the nitrogen atoms of the 2-quin ligand are coordinating to the tin atoms for all of the 12 complexes. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.03.046