adamantane-2,6-dione-1,5-dicarboxylic acid | 41585-35-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: adamantane-2,6-dione-1,5-dicarboxylic acid
• 英文别名: Adamantan-dion-(2,6)-dicarbonsaeure-(1,5)；4,8-dioxo-adamantane-1,3-dicarboxylic acid；4,8-Dioxo-adamantan-1,3-dicarbonsaeure；4,8-Dioxo-tricyclo[3,3,1,1^3,7]decan-dicarbonsaeure-(1,3)；Adamantane-2,6-dione-1,5-dicarboxylic；4,8-dioxoadamantane-1,3-dicarboxylic acid
• CAS: 41585-35-7
• 化学式: C₁₂H₁₂O₆
• 分子量: 252.224
• InChiKey: OPQVOOASZKDKBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  109
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  adamantane-2,6-dione-1,5-dicarboxylic acid 在 氢氧化钾 、 一水合肼 作用下， 以 二乙二醇 为溶剂， 以78%的产率得到bis(pyrazolone-5)-<1,2-b,e>adamantane
  参考文献：
  名称：

  Adamantane and its derivatives. 1. Hydrazones and pyrazolones of adamantane

  摘要：

  DOI：

  10.1007/bf00503563
• 作为产物：
  描述：

  dimethyl adamantane-2,6-dione-1,5-dicarboxylate 在 盐酸 、 溶剂黄146 作用下， 生成 adamantane-2,6-dione-1,5-dicarboxylic acid
  参考文献：
  名称：

  Prelog; Seiwerth, Chemische Berichte, 1941, vol. 74, p. 1644,1647

  摘要：

  DOI：

文献信息

• Compound having silsesquioxane skeleton and its polymer
  申请人：Inagaki Jyun-ichi

  公开号：US20050009982A1

  公开（公告）日：2005-01-13

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, and Q 2 is a group represented by Formula (2) wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, —CH═CR—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in Claim 1.

  本发明涉及一种由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是苯基，可能具有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己基、环己烯基或苯基，其中可选的氢原子可被卤素或具有1至5个碳原子的烷基取代；Q2是由式（2）表示的基团，其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己亚基、1,4-环己烯亚基、具有6至10个碳原子的缩合环基团，为二价基团，或1,4-苯亚基，Z0至Z3独立地为单键、—CH═CR—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。式（1）中的Y1是权利要求1中定义的基团。
• Verification of translation
  申请人：Inagaki Jyun-ichi

  公开号：US20070190344A1

  公开（公告）日：2007-08-16

  A compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q 2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, and A 1 to A 4 , Z 0 to Z 4 and Y 1 are defined in the specification.

  公式（1）所表示的化合物和使用该化合物制得的聚合物：其中R1是苯基，可以有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己烯基或苯基，其中可选氢原子可以被卤素或具有1至5个碳原子的烷基所取代；Q2是由公式（2）表示的基团：其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4、Z0至Z4和Y1在规范中有定义。
• COMPOUND HAVING SILSESQUIOXANE SKELETON AND ITS POLYMER
  申请人：INAGAKI Jyun-ichi

  公开号：US20120178894A1

  公开（公告）日：2012-07-12

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, <—Z 0 A 1 -Z 1  l A 2 -Z 2  m A 3 -Z 3  n A 4  p -Z 4 —  (2) and Q 2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in claim 1.

  本发明涉及一种由公式（1）表示的化合物以及使用该化合物获得的聚合物：其中R1是苯基，可以具有取代基，Q1是氢、卤素、1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己烯基或苯基，其中可选的氢原子可以被卤素或1至5个碳原子的烷基所取代，<—Z0A1-Z1lA2-Z2mA3-Z3nA4p-Z4—（2）和Q2是由公式（2）表示的基团：其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己基、1,4-环己烯基、具有6至10个碳原子的紧凑环基团，或1,4-苯基，Z0至Z3独立地为单键、CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。公式（1）中的Y1是权利要求1中定义的基团。
• Varnish for forming liquid crystal alignment layer and liquid crystal display element using the same
  申请人：Hattori Takayuki

  公开号：US20060204680A1

  公开（公告）日：2006-09-14

  A varnish for forming a liquid crystal alignment layer is prepared by formulating a polymer obtained by using a silsesquioxane derivative represented by the formula (1), and a solvent. In the formula (1), R independently represents an unsubstituted phenyl, cyclopentyl, cyclohexyl, or t-butyl group, and Y 1 independently represents a group selected from the following formulae (a-1) to (a-6).

  通过配制由式（1）表示的硅倍半氧烷衍生物和溶剂得到的聚合物，制备出一种用于形成液晶配位层的清漆。 在式 (1) 中，R 分别代表未取代的苯基、环戊基、环己基或叔丁基，而 Y 1 独立地代表选自下式（a-1）至（a-6）的基团。
• Moiseev,I.K. et al., Journal of Organic Chemistry USSR (English Translation), 1979, vol. 15, p. 2120 - 2122
  作者：Moiseev,I.K. et al.

  DOI：——

  日期：——