(3E,5E)-2-Methyl-dodeca-3,5-diene | 55638-51-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: (3E,5E)-2-Methyl-dodeca-3,5-diene
• 英文别名: 2-Methyl-3,5-dodecadiene；2-methyldodeca-3,5-diene
• CAS: 55638-51-2
• 化学式: C₁₃H₂₄
• 分子量: 180.334
• InChiKey: HULVBFBDOCMWOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  在 盐酸 作用下， 以 四氢呋喃 为溶剂， 反应 18.0h， 生成 (3E,5E)-2-Methyl-dodeca-3,5-diene
  参考文献：
  名称：

  Insertions of silylated carbenoids into vinylzirconocene chlorides. A convergent route to silyl-substituted allylzirconium reagents

  摘要：

  A convergent route to allylzirconocene reagents by insertion of silyl-substituted carbenoids LiCR(SiMe3)(Cl) into vinylzirconocene chlorides is reported. The product silylated allylzirconocenes react with aldehydes and ketones with high anti-selectivity to afford vinyl- (R=H) or allyl- (R=Me, Pr) silanes which may be converted into 4,5-trans-disubstitituted gamma-lactones and stereodefined dienes. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)01982-6

文献信息

• Insertions of silylated carbenoids into vinylzirconocene chlorides. A convergent route to silyl-substituted allylzirconium reagents
  作者：Alexander N Kasatkin、Richard J Whitby

  DOI：10.1016/s0040-4039(99)01982-6

  日期：1999.12

  A convergent route to allylzirconocene reagents by insertion of silyl-substituted carbenoids LiCR(SiMe3)(Cl) into vinylzirconocene chlorides is reported. The product silylated allylzirconocenes react with aldehydes and ketones with high anti-selectivity to afford vinyl- (R=H) or allyl- (R=Me, Pr) silanes which may be converted into 4,5-trans-disubstitituted gamma-lactones and stereodefined dienes. (C) 1999 Elsevier Science Ltd. All rights reserved.