1,1,2-Tribromo-oct-1-en-3-ol

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: 1,1,2-Tribromo-oct-1-en-3-ol
• 英文别名: 1,1,2-Tribromooct-1-en-3-ol
• 化学式: C₈H₁₃Br₃O
• 分子量: 364.903
• InChiKey: OMXFNJKEFPNNIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 1,1,2-Tribromo-oct-1-en-3-ol 在 吡啶 作用下， 反应 1.5h， 以4 mg的产率得到Acetic acid 1-tribromovinyl-hexyl ester
  参考文献：
  名称：

  New Acetyl Derivatives from Antarctic Delisea fimbriata

  摘要：

  Compounds with three characteristic skeletons of members of the family Bonnemaisoneaceae were found to coexist in the alga Delisea fimbriata. The two new acetates 1 and 2a were also isolated; this is the first isolation of acetates from this genus. The structures, chemical transformation, and biogenetic significance of 1 and 2a are described.

  DOI：

  10.1021/np960175f
• 作为产物：
  描述：

  1,1,2-三溴-1-辛烯-3-酮 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 反应 1.0h， 以10 mg的产率得到1,1,2-Tribromo-oct-1-en-3-ol
  参考文献：
  名称：

  New Acetyl Derivatives from Antarctic Delisea fimbriata

  摘要：

  Compounds with three characteristic skeletons of members of the family Bonnemaisoneaceae were found to coexist in the alga Delisea fimbriata. The two new acetates 1 and 2a were also isolated; this is the first isolation of acetates from this genus. The structures, chemical transformation, and biogenetic significance of 1 and 2a are described.

  DOI：

  10.1021/np960175f

文献信息

• New Acetyl Derivatives from Antarctic <i>Delisea </i><i>fimbriata</i>
  作者：Mercedes Cueto、José Darias、Aurelio San-Martín、Juana Rovirosa

  DOI：10.1021/np960175f

  日期：1997.3.1

  Compounds with three characteristic skeletons of members of the family Bonnemaisoneaceae were found to coexist in the alga Delisea fimbriata. The two new acetates 1 and 2a were also isolated; this is the first isolation of acetates from this genus. The structures, chemical transformation, and biogenetic significance of 1 and 2a are described.