Boll Weevil pheromone | 41370-30-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Boll Weevil pheromone
• 英文别名: grandlure IV；(3,3-Dimethylcyclohexyliden)-acetaldehyd；3,3-Dimethylcyclohexylidenmethylaldehyd；3,3-Dimethylcyclohexyliden-acetaldehyd；Acetaldehyde, 2-(3,3-dimethylcyclohexylidene)-, (2E)-；2-(3,3-dimethylcyclohexylidene)acetaldehyde
• CAS: 41370-30-3
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: TYHKWUGMKWVPDI-UHFFFAOYSA-N

物化性质

• 沸点：
  226.6±9.0 °C(Predicted)
• 密度：
  0.955±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  [1-(1-Chloro-1-methyl-ethyl)-4-methylene-hex-5-enylsulfanyl]-benzene 在 manganese(IV) oxide 、 sodium hydroxide 、 氨 、 lithium 、 tin(ll) chloride 作用下， 以 乙醇 、 正己烷 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 41.0h， 生成 Boll Weevil pheromone
  参考文献：
  名称：

  由月桂烯合成的新的to丁烷

  摘要：

  my丁烷骨架是由月桂烯通过酸催化的苯磺酰氯加合物和该环氧化物以生物遗传类型的方式立体选择性地形成的。据报道，它可用于合成两种啶烷型单萜，棉铃象甲信息素的醛组分和在红藻中发现的二醇。

  DOI：

  10.1016/s0040-4039(00)87138-5

文献信息

• Process of production of 1-(5,5-dimethylcyclohex-1-en-1-yl)ethanone and 1-(5,5-dimethylcyclohex-6-en-1-yl )ethanone
  申请人：DSM IP ASSETS B.V.

  公开号：US10005710B2

  公开（公告）日：2018-06-26

  The present invention relates to an improved method for producing of 1-(5,5-dimethylcyclohex-1-en-1-yl)ethanone and 1-(5,5-dimethylcyclohex-6-en-1-yl)ethanone.

  本发明涉及一种生产 1-(5,5-二甲基环己-1-烯-1-基)乙酮和 1-(5,5-二甲基环己-6-烯-1-基)乙酮的改进方法。
• Composition of grandlure and dichlorvos for attracting and killing boll weevils in boll weevil traps
  申请人：Plato Alfred Thomas

  公开号：US20050147634A1

  公开（公告）日：2005-07-07

  Compositions and methods for attracting, capturing and killing populations of cotton boll weevils ( Anthonomus grandis Boh. ) in boll weevil traps are disclosed. With respect to the attraction and capture of boll weevils with Grandlure, the synthetic pheromone of the cotton boll weevil, there is generally an increased number of boll weevils captured in the trap cylinder when an insecticide dispenser is included in the trap cylinder to kill the weevils and thus prevent their escape. Additionally, dead boll weevils are more accurately counted than live boll weevils. The compound dichlorvos (2,2-dichlorovinyl dimethyl phosphate or DDVP) is the most preferred among those few insecticides that can be used in traps for killing and preventing weevil escapes. This is also the preferred insecticide when combined with Grandlure in a single dispenser to kill boll weevils or inhibit their ability to develop normally and reproduce. The single Grandlure dichlorvos dispenser provides for significant savings in labor expenses in large area trapping and eradication programs and significantly reduces the disposal of waste materials from spent dispensers.

  用于吸引、捕捉和杀死棉铃象鼻虫（Anthonomus grandis Boh. Anthonomus grandis Boh. 棉铃象鼻虫）的组合物和方法。关于用棉铃象鼻虫的合成信息素 Grandlure 吸引和捕获棉铃象鼻虫，如果在诱捕筒中加入杀虫剂喷洒器杀死象鼻虫，从而防止它们逃跑，则诱捕筒中捕获的棉铃象鼻虫数量通常会增加。此外，死棉铃虫的计数比活棉铃虫更准确。敌敌畏（2,2-二氯乙烯基二甲基磷酸酯或 DDVP）是少数几种可用于诱捕器以杀死并防止象鼻虫逃逸的杀虫剂中最受欢迎的一种。当与格兰富（Grandlure）结合使用时，这也是杀死棉铃象鼻虫或抑制其正常发育和繁殖能力的首选杀虫剂。在大面积诱捕和根除计划中，单一的敌敌畏喷洒器可大大节省劳动力支出，并显著减少废喷洒器产生的废料处理量。
• Synthesis of aldehydes from dihydro-1,3-oxazines
  作者：A. I. Meyers、A. Nabeya、H. W. Adickes、I. R. Politzer、G. R. Malone、A. C. Kovelesky、R. L. Nolen、R. C. Portnoy

  DOI：10.1021/jo00941a008

  日期：1973.1
• A new method for the bishomologation of carbonyl compounds to α,β-unsaturated aldehydes via the [3,3]sigmatropic rearrangement of allylic thionocarbamates
  作者：Takeshi Nakai、Tetsuya Mimura、Akira Ari-Izumi

  DOI：10.1016/s0040-4039(01)83783-7

  日期：1977.1
• New synthetic methods for .gamma.-geraniol, boll weevil pheromone, and .alpha.-damascone employing 2-(hydroxymethyl)-4-(phenylthio)-1-butene as a building block
  作者：Tadakatsu Mandai、Koji Mizobuchi、Mikio Kawada、Junzo Otera

  DOI：10.1021/jo00192a037

  日期：1984.9