6,12,18,24,30-pentaoxa-3,9,15,21,27,33-hexathia-pentatriacontane-1,35-diol | 121262-74-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6,12,18,24,30-pentaoxa-3,9,15,21,27,33-hexathia-pentatriacontane-1,35-diol
• 英文别名: 1.35-Dihydroxy-6.12.18.24.30-pentaoxa-3.9.15.21.27.33-hexathia-pentatriacontan；6,12,18,24,30-Pentaoxa-3,9,15,21,27,33-hexathia-pentatriacontan-1,35-diol；2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-Hydroxyethylsulfanyl)ethoxy]ethylsulfanyl]ethoxy]ethylsulfanyl]ethoxy]ethylsulfanyl]ethoxy]ethylsulfanyl]ethoxy]ethylsulfanyl]ethanol；2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hydroxyethylsulfanyl)ethoxy]ethylsulfanyl]ethoxy]ethylsulfanyl]ethoxy]ethylsulfanyl]ethoxy]ethylsulfanyl]ethoxy]ethylsulfanyl]ethanol
• CAS: 121262-74-6
• 化学式: C₂₄H₅₀O₇S₆
• 分子量: 643.053
• InChiKey: QWLBPHZCVCWQEM-UHFFFAOYSA-N

物化性质

• 沸点：
  757.6±60.0 °C(Predicted)
• 密度：
  1.201±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  37
• 可旋转键数：
  34
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  238
• 氢给体数：
  2
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  6,12,18,24,30-pentaoxa-3,9,15,21,27,33-hexathia-pentatriacontane-1,35-diol 在 氯化亚砜 、 氯仿 作用下， 生成 1,35-dichloro-6,12,18,24,30-pentaoxa-3,9,15,21,27,33-hexathia-pentatriacontane
  参考文献：
  名称：

  Policy analysis in the presence of distorting taxes

  摘要：

  This article first describes the new literature in environmental economics on the so-called "double-dividend" and then explores its implications for a broad range of economic issues. This literature reveals that in a second-best, general-equilibrium setting environmental measures raise costs and prices and thereby reduce the real wage. This rise in the cost of living reduces slightly the quantity of labor supplied in an already highly distorted labor market, giving rise to losses in social welfare that can be large relative to the basic gains from a cleaner environment. These losses can be offset to some extent by using revenues (if any) from the environmental programs to reduce existing taxes on labor This same line of analysis applies to many programs and institutions in the economy that mise the cost of living: tariffs and quotas on imports, agricultural price-support programs, monopoly pricing, programs of occupational licensure that limit entry, and many others. Thus, traditional, partial-equilibrium benefit-cost analysis appears, in many instances, to have unwittingly omitted from the calculations a potentially quite significant class of social costs. (C) 2000 by the Association for Public Policy and Management.

  DOI：

  10.1002/1520-6688(200023)19:4<603::aid-pam5>3.0.co;2-3
• 作为产物：
  描述：

  2-[2-(2-mercapto-ethoxy)-ethylsulfanyl]-ethanol 、 1,17-dichloro-3,9,15-trioxa-6,12-dithia-heptadecane 在 sodium ethanolate 作用下， 生成 6,12,18,24,30-pentaoxa-3,9,15,21,27,33-hexathia-pentatriacontane-1,35-diol
  参考文献：
  名称：

  Policy analysis in the presence of distorting taxes

  摘要：

  This article first describes the new literature in environmental economics on the so-called "double-dividend" and then explores its implications for a broad range of economic issues. This literature reveals that in a second-best, general-equilibrium setting environmental measures raise costs and prices and thereby reduce the real wage. This rise in the cost of living reduces slightly the quantity of labor supplied in an already highly distorted labor market, giving rise to losses in social welfare that can be large relative to the basic gains from a cleaner environment. These losses can be offset to some extent by using revenues (if any) from the environmental programs to reduce existing taxes on labor This same line of analysis applies to many programs and institutions in the economy that mise the cost of living: tariffs and quotas on imports, agricultural price-support programs, monopoly pricing, programs of occupational licensure that limit entry, and many others. Thus, traditional, partial-equilibrium benefit-cost analysis appears, in many instances, to have unwittingly omitted from the calculations a potentially quite significant class of social costs. (C) 2000 by the Association for Public Policy and Management.

  DOI：

  10.1002/1520-6688(200023)19:4<603::aid-pam5>3.0.co;2-3

文献信息

• Degradation of Sulfur Mustard on KF/Al₂O₃ Supports: Insights into the Products and the Reactions Mechanisms
  作者：Yossi Zafrani、Michael Goldvaser、Shai Dagan、Liron Feldberg、Dana Mizrahi、Daniel Waysbort、Eytan Gershonov、Ishay Columbus

  DOI：10.1021/jo901713c

  日期：2009.11.6

  The degradation of the warfare agent sulfur Mustard (HD) adsorbed onto KIF/Al2O3 sorbents is described. These processes were explored by MAS NMR. using C-13-labeled sulfur mustard (HD*) and LC-MS techniques. Out study on the detoxification of this blister agent showed the formation of nontoxic substitution and less-toxic elimination products (t(1/2) = 3.5-355 h) Interestingly, the reaction rates Were found to be affected by MAS conditions, i.e., by a centrifugation effect. The products and the mechanisms of these processes tire discussed.