sodium diisobutyldithiophosphinate | 13360-78-6

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机钠
• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: sodium diisobutyldithiophosphinate
• 英文别名: sodium diisobuthyldithiophosphinate；iso-Bu2PS2Na；Na(iso-Bu2PS2)；Sodium bis(2-methylpropyl)phosphinodithioate；sodium;bis(2-methylpropyl)-sulfanylidene-sulfido-λ5-phosphane
• CAS: 13360-78-6
• 化学式: C₈H₁₈PS₂*Na
• 分子量: 232.326
• InChiKey: OJNSBQOHIIYIQN-UHFFFAOYSA-M

物化性质

• 沸点：
  378.5℃[at 101 325 Pa]
• 密度：
  1,14 g/cm3
• 闪点：
  93 °C
• LogP：
  -1.64 at 23℃
• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  0.24
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  33.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• TSCA：
  No
• 危险品标志：
  Xi
• 安全说明：
  S26,S36,S36/37/39
• 危险类别码：
  R36/37/38,R36/38
• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  sodium diisobutyldithiophosphinate 在 HCl 作用下， 以 水 、 甲苯 为溶剂， 生成 Cd(2,2'-Bipy)[(i-C4H9)2PS2]2
  参考文献：
  名称：

  摘要：

  Volatile mixed-ligand compounds of Cd(i-Bu2PS2)(2) with Phen, 2,2'-Bipy, and 4,4'-Bipy were synthesized. Their single crystals were grown. X-ray diffraction data (a CAD4 diffractometer, MoKalpha radiation, 2140 F-hkl, R = 0.0251) were used to determine the structure of [Cd(4,4'-Bipy)(i-Bu2PS2)(2)]. The crystals are monoclinic: a = 14.678(3) Angstrom, b = 11.866(2) Angstrom, c = 19.655(4) Angstrom, beta = 102.17(3)degrees, V = 3346(1) Angstrom (3), Z = 4, rho (calcd) = 1.364 g/cm(3), space group C2/c. The structure is built from linear polymeric chains arranged along the [010] direction. The coordination polyhedron of the Cd atom is a distorted octahedron (4S + 2N). The thermal properties of these compounds, studied both in air and in vacuo, allow one to use them for preparing CdS films by chemical precipitation from the gas phase.

  DOI：

  10.1023/a:1011329313925

文献信息

• Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS 2 - , C4H8NCS 2 - ; A = NH 4 + , Et4N+)
  作者：Yu. A. Bryleva、V. F. Plyusnin、L. A. Glinskaya、A. S. Kupryakov、I. V. Korol’kov、D. A. Piryazev、S. V. Larionov

  DOI：10.1134/s1070328417020026

  日期：2017.3

  Complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS -2 , C4H8NCS -2 ; A = NH +4 , Et4N+) are synthesized. The crystal structure of compound [Gd(Phen)(iso-Bu2PS2)3] · MeCN is determined by X-ray diffraction analysis (CIF file CCDC no. 1455418). The structure consists of molecules of the mononuclear complex [Gd(Phen)(iso-Bu2PS2)3] and MeCN. The coordination polyhedron N2S6 of the Gd atom is a distorted

  配合物（A）[Gd（L）4 ]和[Gd（Phen）（L）3 ]（L = iso- Bu 2 PS - 2，C 4 H 8 NCS - 2； A = NH + 4，Et 4 N +）被合成。化合物[Gd（Phen）（iso -Bu 2 PS 2）3 ]·MeCN的晶体结构通过X射线衍射分析（CIF文件CCDC No.1455418）确定。该结构由单核络合物[Gd（Phen）（iso -Bu 2 PS 2）3的分子 ]和MeCN。Gd原子的配位多面体N 2 S 6是扭曲的反棱镜。复合物在400-600 nm范围内显示出磷光。配位体C 4 H 8 NCS - 2（23336 cm –1）和iso -Bu 2 PS - 2（23506 cm –1）三重态能级的能量由配合物（A）[Gd（ L）4 ]在冷冻乙醇（77 K）中。
• Synthesis and X-ray single crystal structures of bis(diisobutyldithiophosphinato)cadmium(II) or zinc(II): Potential single-source precursors for II/VI materials
  作者：C Byrom、M.A Malik、P O’Brien、A.J.P White、D.J Williams

  DOI：10.1016/s0277-5387(99)00352-6

  日期：2000.1

  Abstract Bis(diisobutyldithiophosphinato)cadmium(II) (1) and bis(diisobutyldithiophosphinato)zinc(II) (2) have been synthesised and their X-ray single crystal structures determined. Both compounds have been used as precursors to grow thin films of CdS and ZnS, respectively, by low-pressure metal organic chemical vapour deposition (LP-MOCVD).

  摘要合成了双（二异丁基二硫代膦酰基）镉（II）和双（二异丁基二硫代膦酰基）锌（II）（2）并确定了它们的X射线单晶结构。通过低压金属有机化学气相沉积（LP-MOCVD），这两种化合物已分别用作生长CdS和ZnS薄膜的前体。
• LIGAND EXCHANGE THERMOCHROMIC SYSTEMS AND HIGH E LIGANDS FOR SAME
  申请人：Byker J. Harlan

  公开号：US20080105851A1

  公开（公告）日：2008-05-08

  Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes. In accordance with certain aspects of the present invention, a thermochromic system is disclosed comprising a transition metal ion and a ligand wherein the ligand comprises a nitrogen-containing five or six membered heterocyclic compound that coordinates through the nitrogen atom to the transition metal ion in a HεMLC formed between the transition metal ion and the ligand. In accordance with other aspects of the present invention, thermochromic systems are disclosed comprising a transition metal ion with particularly useful ligands, such as phosphine compounds, tridentate ligands that coordinate through three nitrogen atoms, bidentate ligands, or ortho hindered pyridine monodentate ligands.

  本文描述了具有热致变色性质的配体交换（LETC）系统，当系统的温度可逆变化时，电磁辐射吸收率也可逆变化。所述的LETC系统包括一个或多个过渡金属离子，其经历热诱导的配位或配位环境的变化，从而使系统随着温度变化而改变吸收电磁辐射的能力。根据本发明的某些方面，公开了包括过渡金属离子和配体的热致变色系统，其中配体包括通过氮原子与过渡金属离子形成的HεMLC（配体与过渡金属离子之间的配位键）的含氮五元或六元杂环化合物。根据本发明的其他方面，公开了包括具有特别有用的配体的过渡金属离子的热致变色系统，例如膦化合物、通过三个氮原子配位的三齿配体、双齿配体或邻位受阻的吡啶单齿配体。
• LIGAND EXCHANGE THERMOCHROMIC SYSTEMS CONTAINING EXCHANGE METALS
  申请人：Byker J. Harlan

  公开号：US20080106781A1

  公开（公告）日：2008-05-08

  Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes. In accordance with one aspect of the present invention, a thermochromic system is disclosed comprising a first metal ion and a second metal ion and at least one ligand that complexes with the first metal ion to form a LεMLC and complexes with the second metal ion to form a HεMLC wherein an increase in temperature of the system results in a reversible net increase in its ability to absorb light energy in the 400 nm to 1400 nm range due to the ligand transferring from the first metal ion to the second metal ion.

  本文介绍了一种具有热致变色特性的配体交换系统，当系统的温度可逆变化时，其吸收电磁辐射的能力也可逆变化。所述的LETC系统包括一个或多个过渡金属离子，其在过渡金属离子周围的络合或配位发生热诱导变化，从而使系统随着温度变化而改变吸收电磁辐射的能力。根据本发明的一个方面，公开了一种热致变色系统，包括第一金属离子和第二金属离子以及至少一个配体，该配体与第一金属离子形成LεMLC配合物，并与第二金属离子形成HεMLC配合物，系统温度的升高导致可逆的净吸收光能力增加，范围为400纳米至1400纳米，这是由于配体从第一金属离子转移到第二金属离子造成的。
• LIGAND EXCHANGE THERMOCHROMIC, (LETC), SYSTEMS
  申请人：Byker J. Harlan

  公开号：US20080100902A1

  公开（公告）日：2008-05-01

  Ligand exchange of thermochromic, LETC, systems exhibiting a reversible change in absorbance of electromagnetic radiation as the temperature of the system is reversibly changed are described. The described LETC systems include one or more than one transition metal ion, which experiences thermally induced changes in the nature of the complexation or coordination around the transition metal ion(s) and, thereby, the system changes its ability to absorb electromagnetic radiation as the temperature changes.

  本文介绍了一种热致变色（LETC）系统的配体交换方法，该系统在温度可逆变化时显示出电磁辐射吸收的可逆变化。所述LETC系统包括一个或多个过渡金属离子，其在过渡金属离子周围的配位或络合性质发生热诱导变化，从而使系统在温度变化时改变吸收电磁辐射的能力。