diprop-2-ynyl fumarate | 53024-63-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: diprop-2-ynyl fumarate
• 英文别名: Malein-(od. Fumar-)saeure-dipropinylester；Bis(prop-2-ynyl) but-2-enedioate
• CAS: 53024-63-8
• 化学式: C₁₀H₈O₄
• 分子量: 192.171
• InChiKey: UDTFMMZGEOHGNU-UHFFFAOYSA-N

物化性质

• 沸点：
  268.5±30.0 °C(Predicted)
• 密度：
  1.188±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diprop-2-ynyl fumarate 在 水 、 5-甲氧基-1,3,4-三苯基-4,5-二氢-1H-1,2,4-三唑 作用下， 以 乙二醇二甲醚 为溶剂， 反应 2.0h， 以68%的产率得到二丙-2-炔基丁烷二酸酯
  参考文献：
  名称：

  Transfer hydrogenation promoted by N-heterocyclic carbene and water

  摘要：

  N-杂环卡宾（NHCs）促进了各种活化的C=C、C=N和N=N键的氢转移反应，水是质子源。

  DOI：

  10.1039/c5cc05117g
• 作为产物：
  描述：

  2-丙炔-1-醇 、 fumaric acid 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 48.0h， 以22%的产率得到diprop-2-ynyl fumarate
  参考文献：
  名称：

  Transfer hydrogenation promoted by N-heterocyclic carbene and water

  摘要：

  N-杂环卡宾（NHCs）促进了各种活化的C=C、C=N和N=N键的氢转移反应，水是质子源。

  DOI：

  10.1039/c5cc05117g

文献信息

• Oil based blends of interpolymers of ethylene/alpha-olefins
  申请人：Soediono Mahalia

  公开号：US20070112127A1

  公开（公告）日：2007-05-17

  Polymer blends comprise at least one ethylene/α-olefin interpolymer and one or more oil. The oil can be an aromatic oil, napththenic oil, paraffinic oil or a combination thereof. The ethylene/α-olefin interpolymers are random block copolymers comprising at least a hard block and at least a soft block. The resulting blends can be used to make flexible molded articles.

  聚合物混合物至少包含一种乙烯/α-烯烃共聚物和一种或多种油。该油可以是芳香油、萘烷油、石蜡油或其组合。乙烯/α-烯烃共聚物是随机嵌段共聚物，包括至少一个硬块和至少一个软块。由此得到的混合物可用于制造柔性模塑制品。
• Synthesis and characterization of new rhodium–cobalt mixed-metal octahedral linked clusters containing η2-diyne ligands
  作者：Bao-Hua Zhu、Bin Hu、Wei-Qiang Zhang、Yu-Hua Zhang、Yuan-Qi Yin、Jie Sun

  DOI：10.1016/s0022-328x(03)00630-2

  日期：2003.9

  (13)) in n-hexane at room temperature, respectively. The acetylene moieties of diyne ligands insert into the CoCo bonds of two tetranuclear clusters to give linked octahedral clusters containing two [Rh2Co2C2] units. The structure of cluster 1 was determined by single-crystal X-ray diffraction analysis and all clusters were characterized by elemental analysis (C/H), IR and 1H-NMR spectroscopy.

  六个新RhCo混合金属连接簇配合物的[Rh 2共2（CO）8（μ-CO）2（μ 4，η 2 -HCCCH 2 O）] 2 R（R = C ^ 6 ħ 4 -1,4（1）; C 6 H 4 -1,4（C（O））2（2）;（C（O）CH 2）2（3）;（C（O）CH）2（4）;（C（O））2 CH 2（5）;（C（O））2（6））已从[Rh中的反应合成2共2（CO）12 ]（7）与合适的二炔化合物[（HCCCH 2 CO）] 2 R（R = C ^ 6 ħ 4 -1,4-（8）; C 6 H 4 -1,4（C（O））2（9）;（C（O）CH 2）2（10）;（C（O）CH）2（11）;（C（ O））2 CH 2（12）;（C（O））2（13））在n中己烷分别在室温下。二炔配体的乙炔部分插入两个四核簇的CoCo键中，得到连接的包含两个[Rh 2 Co 2 C 2 ]单元的八面体簇。簇
• Oriented polymeric films and process for enhanced orientation of polymeric films
  申请人：W.R. Grace & Co.-Conn.

  公开号：EP0322196A2

  公开（公告）日：1989-06-28

  Described is the presence of both a pro-rad linking agent and irradiation such as electron beam irradia­tion, in the manufacturing process for making an oriented, i.e. heat-shrinkable, polymeric film. The presence of both results in an amount of cross--linking that is effective to accomplish an increased orientation rate during manufactur­ing.

  描述的是在制造取向（即热收缩）聚合薄膜的生产过程中，同时使用促辐射连接剂和辐照（如电子束辐照）。两者同时使用可产生一定量的交联，从而有效地提高生产过程中的取向率。
• Graft copolymer and process for producing the same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0490269A1

  公开（公告）日：1992-06-17

  There is provided a process for producing a styrenic graft copolymer which comprises coplymerizing a styrenic monomer and a styrenic monomer having a hydrocarbon radical with an unsaturated bond in the presence of a catalyst comprising as primary ingredient (A) a transition metal compound and (B) a contact product of an organoaluminum compound and a condensation agent or (C) a compound which produces an ionic complex by reacting with the above-mentioned transition metal compound and subsequently graft polymerizing an ethylenically unsaturated monomer onto the resultant styrenic copolymer. The above-described styrenic graft copolymer is greatly improved in terms of compatibility, adhesivity, coatability and wettability while preserving heat resistance and chemical resistance thereof, and thus effective as a variety of constructional materials and compatibilizing agents. Furthermore, the composition or multi-layer material comprising the above-mentioned styrenic graft copolymer is widely utilized in a variety of application field including film, sheet, especially stampable sheet, container, packaging material, automobile parts, electrical and electronic parts, etc.

  提供了一种生产苯乙烯接枝共聚物的工艺，该工艺包括在催化剂存在下，使苯乙烯单体和具有不饱和键烃基的苯乙烯单体共聚，催化剂的主要成分包括(A)过渡金属化合物和(B)有机铝化合物与缩合剂的接触产物或(C)通过与上述过渡金属化合物反应产生离子络合物的化合物，然后将乙烯基不饱和单体接枝聚合到生成的苯乙烯共聚物上。上述过渡金属化合物反应生成离子络合物的化合物，然后将乙烯不饱和单体接枝聚合到生成的苯乙烯共聚物上。 上述苯乙烯接枝共聚物在保持其耐热性和耐化学性的同时，在相容性、粘合性、涂覆性和润湿性方面得到了极大的改善，因此可以有效地用作各种建筑材料和相容剂。此外，由上述苯乙烯接枝共聚物组成的组合物或多层材料可广泛应用于各种应用领域，包括薄膜、片材，尤其是可冲压片材、容器、包装材料、汽车零件、电子电气零件等。
• STYRENIC COPOLYMER AND PRODUCTION THEREOF
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0511407A1

  公开（公告）日：1992-11-04

  A styrenic copolymer having at least one structural unit represented by general formula (I) and either a structural unit represented by general formula (II) or a structural unit represented by general formula (IX), the content of the unit (II) or the unit (IX) being 0.01 to 99.9 mole %. In these formulae each symbol is as defined in the specification. This copolymer is highly syndiotactic in the stereoregularity of the chain composed of the structural units (I) and is excellent in the adhesion and compatibility with other resins.

  一种苯乙烯共聚物，至少有一个结构单元由通式(I)和一个结构单元由通式(II)或一个结构单元由通式(IX)表示，单元(II)或单元(IX)的含量为 0.01 至 99.9 摩尔%。在这些式子中，每个符号都与说明书中的定义相同。这种共聚物由结构单元（I）组成的链具有高度的立体均匀性，与其他树脂的粘合性和相容性极佳。