Azuleno[1,2-d][1,3]dithiole-2-thione | 1451059-79-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: Azuleno[1,2-d][1,3]dithiole-2-thione
• 英文别名: azuleno[1,2-d][1,3]dithiole-2-thione
• CAS: 1451059-79-2
• 化学式: C₁₁H₆S₃
• 分子量: 234.367
• InChiKey: UKUAYPMODISFIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  82.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  奥苷菊环 在 吡啶 、 lithium aluminium tetrahydride 、 cyclo-tetradecasulfur 作用下， 以 四氢呋喃 为溶剂， 反应 79.67h， 生成 Azuleno[1,2-d][1,3]dithiole-2-thione
  参考文献：
  名称：

  AZULENOPENTATHIEPIN: PREPARATION AND CONVERSION INTO AZULENES WITH SULFUR GROUPS AT THE 1- AND 2-POSITIONS

  摘要：

  Azulenopentathiepin was prepared by the reaction of azulene with elemental sulfur in boiling pyridine. Bis(thiolate) generated from the pentathiepin reacted with electrophiles such as iodomethane, methyl chloroformate, N,N'-carbonyldiimidazole and N,N'-thiocarbonyldiimidazole to afford the corresponding azulene derivatives. Desulfuration of the pentathiepin and the successive reaction with DMAD or a Pd(0) reagent afforded a 1,4-dithiin compound or Pd complexes.

  DOI：

  10.3987/com-12-s(n)80

文献信息

• AZULENOPENTATHIEPIN: PREPARATION AND CONVERSION INTO AZULENES WITH SULFUR GROUPS AT THE 1- AND 2-POSITIONS
  作者：Ohki Sato、Atsushi Sakai、Masami Aoki、Takaaki Kuramochi、Juzo Nakayama

  DOI：10.3987/com-12-s(n)80

  日期：——

  Azulenopentathiepin was prepared by the reaction of azulene with elemental sulfur in boiling pyridine. Bis(thiolate) generated from the pentathiepin reacted with electrophiles such as iodomethane, methyl chloroformate, N,N'-carbonyldiimidazole and N,N'-thiocarbonyldiimidazole to afford the corresponding azulene derivatives. Desulfuration of the pentathiepin and the successive reaction with DMAD or a Pd(0) reagent afforded a 1,4-dithiin compound or Pd complexes.