methylgermyl chloride | 29914-10-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: methylgermyl chloride
• 英文别名: methyl chlorogermane；Methylchlorgerman；Chloromethylgerman；Methylchlorgermaniumhydrid；Chloro(methyl)germane
• CAS: 29914-10-1
• 化学式: CH₅ClGe
• 分子量: 125.094
• InChiKey: AABSEAOIRMIEMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.36
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  methylgermyl chloride 、 氢溴酸 生成 methylgermyl bromide
  参考文献：
  名称：

  Spectra and structure of organogermanes—XXV. Infra-red and Raman spectra of methylgermyl isocyanate

  摘要：

  DOI：

  10.1016/0584-8539(88)80039-4
• 作为产物：
  描述：

  甲基锗烷 、 四氯化锡 生成 methylgermyl chloride
  参考文献：
  名称：

  Spectra and structure of organogermanes—XXV. Infra-red and Raman spectra of methylgermyl isocyanate

  摘要：

  DOI：

  10.1016/0584-8539(88)80039-4

文献信息

• Audett, Judy A. nee Christie; Mackay, Kenneth M., Journal of the Chemical Society, Dalton Transactions
  作者：Audett, Judy A. nee Christie、Mackay, Kenneth M.

  DOI：——

  日期：——
• Transition-metal carbonyl derivatives of the germanes. Part 9. Reactions of tetracarbonyldi(methylgermyl)iron with some covalent halides
  作者：Alan Bonny、Kenneth M. Mackay

  DOI：10.1039/dt9780001569

  日期：——
• Formation and reactions of mono- and di-substituted derivatives of [µ₄-Ge{CO₂(CO)₇}₂], containing functional µ-GeRH or µ-GeRCl groups
  作者：Siew Kim Lee、Kenneth M. Mackay、Brian K. Nicholson

  DOI：10.1039/dt9930000715

  日期：——

  The reaction of [mu4-GeCo2(CO)7}2] 1 with GeRH3 (R = Et or Ph) has been found to give [mu4-GeCo2(CO)7}Co2(CO)6(mu-GeRH)}] 2 or [mu4-GeCo2(CO)6(mu-GeRH)}2] 3 depending on the stoichiometries and conditions. Analogues of 2 or 3 with mu-GeMeCl groups form from 1 and GeMe(Cl)H2. Reaction of 2 with [Co2(CO)8] gives an open cluster with a mu-Ge(R)Co(CO)4 group which readily condenses to a closo-cluster with a Ge2Co4 core. Analogous reactions of 3 with [Co2(CO)8] ultimately give clusters [Co4(mu4-GeR)2mu-GeCo2(CO)7}(CO)10] again via more-open intermediates. Corresponding species are obtained from the mu-GeMeCl compounds and [Co(CO)4]-. An X-ray structure analysis of [Co4(mu4-GeEt)2mu-GeCo2(CO)7}(CO)10] has been performed: triclinic, space group P1BAR, a = 10.617(1), b = 16.895(3), c = 9.822(4) angstrom, alpha = 104.22(2), beta = 94.40(2), gamma = 102.03(1)-degrees, Z = 2, R = 0.027, for 3516 data with I > 2sigma(I). It reveals a structure consisting of a pseudo-octahedral Ge2Co4 unit, with one of the Co-Co bonds edge-bridged by a mu-GeCo2(CO)7 moiety.
• GERLACH R. F.; GRAHAM B. W. L.; MACKAY K. M., J. ORGANOMETAL. CHEM., 1979, 182, NO 2, 285-298
  作者：GERLACH R. F.、 GRAHAM B. W. L.、 MACKAY K. M.

  DOI：——

  日期：——
• Spectra and structure of organogermanes—XXV. Infra-red and Raman spectra of methylgermyl isocyanate
  作者：J.R. Durig、G.M. Attia

  DOI：10.1016/0584-8539(88)80039-4

  日期：1988.1