carbonic acid-(2-ethoxy-ethyl ester)-ethyl ester | 627034-93-9

• 物质功能分类: 有机原料 - 醚类化合物及其衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: carbonic acid-(2-ethoxy-ethyl ester)-ethyl ester
• 英文别名: Kohlensaeure-(2-aethoxy-aethylester)-aethylester；Aethyl-(2-aethoxy-aethyl)-carbonat；ethyl 2-ethoxyethyl carbonate；Carbonic acid, 2-ethoxyethyl ethyl ester；2-ethoxyethyl ethyl carbonate
• CAS: 627034-93-9
• 化学式: C₇H₁₄O₄
• 分子量: 162.186
• InChiKey: UIVHLJQMLWRKJZ-UHFFFAOYSA-N

物化性质

• 沸点：
  194-194.9 °C(Press: 742.7 Torr)
• 密度：
  1.5064 g/cm3(Temp: 25 °C)
• LogP：
  0.928 at 22℃ and pH6.2

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  乙二醇乙醚 、 碳酸二乙酯 在 ZN-0312 T 作用下， 反应 6.0h， 生成 乙醇 、 carbonic acid-(2-ethoxy-ethyl ester)-ethyl ester
  参考文献：
  名称：

  [EN] PROCESS FOR REMOVING AN ALKANOL IMPURITY FROM A DIALKYL CARBONATE STREAM
  [FR] PROCÉDÉ POUR L'ÉLIMINATION D'UNE IMPURETÉ ALCANOL À PARTIR D'UN COURANT DE CARBONATE DE DIALKYLE

  摘要：

  该发明涉及一种从含有二烷基碳酸酯和烷醇杂质的流体中去除烷醇杂质的过程，包括将流体与含有芳基的酯和催化剂接触，以使烷醇杂质与含有芳基的酯发生反应。

  公开号：

  WO2011018448A1

文献信息

• METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR USE IN POLYMERIZATION OF OLEFIN, CATALYST FOR USE IN POLYMERIZATION OF OLEFIN, AND METHOD FOR PRODUCING OLEFIN POLYMER
  申请人：Toho Titanium CO., LTD.

  公开号：EP2876118A1

  公开（公告）日：2015-05-27

  A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds selected from specific aromatic dicarboxylic diesters into contact with each other to effect a reaction, followed by washing, a second step that brings a tetravalent titanium halide compound and one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction, followed by washing, and a third step that brings one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.

  一种生产烯烃聚合用固体催化剂组分的方法可生产出一种新型的烯烃聚合用固体催化剂组分，该组分具有优异的烯烃聚合活性和聚合过程中对氢的活性，并可生产出具有高MFR、高立体规整度和优异刚性的烯烃聚合物。该方法包括第一步，使镁化合物、四价卤化钛化合物和一种或多种选自特定芳香族二羧酸二酯的第一内部电子供体化合物相互接触以发生反应，然后进行洗涤、第二步：使四价卤化钛化合物和一种或多种第二内部电子供体化合物与第一步得到的产物接触，以发生反应，然后进行洗涤；第三步：使一种或多种第三内部电子供体化合物与第二步得到的产物接触，以发生反应。
• SOLID CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINS, CATALYST FOR POLYMERIZATION OF OLEFINS, AND METHOD FOR PRODUCING OLEFIN POLYMER
  申请人：Toho Titanium CO., LTD.

  公开号：EP2902418A1

  公开（公告）日：2015-08-05

  A solid catalyst component for olefin polymerization makes it possible to polymerize an olefin with high polymerization activity when used for an olefin polymerization catalyst, and produce an olefin polymer having a low fine powder content, a low coarse powder content, and a low volatile organic compound (VOC) content in high yield. The solid catalyst component for olefin polymerization is produced by suspending (a) a dialkoxymagnesium, and (b) at least one alcohol selected from ethanol, n-propanol, n-butanol, isopropanol, isobutanol, and t-butanol, in an inert organic solvent so that the total amount of the alcohol is 0.5 to 1.5 parts by mass based on 100 parts by mass of the dialkoxymagnesium, to prepare a suspension, and bringing (c) an internal electron donor and (d) a titanium halide compound into contact with the suspension.

  一种用于烯烃聚合的固体催化剂组分可使烯烃聚合催化剂具有较高的聚合活性，并能高产率地生产出细粉含量低、粗粉含量低和挥发性有机化合物（VOC）含量低的烯烃聚合物。用于烯烃聚合的固体催化剂组分是通过在惰性有机溶剂中悬浮 (a) 二羰基镁和 (b) 至少一种选自乙醇、正丙醇、正丁醇、异丙醇、异丁醇和正丁醇的醇，使醇的总量为 0.5 至 1.5 质量份（以 100 质量份的二烷氧基镁为基准），以制备悬浮液，并使(c) 内部电子供体和(d) 卤化钛化合物与悬浮液接触。
• PRODUCTION METHOD FOR SOLID CATALYST COMPONENT FOR POLYMERIZING OLEFINS, CATALYST FOR POLYMERIZING OLEFINS, AND PRODUCTION METHOD FOR POLYMERIZED OLEFINS
  申请人：TOHO TITANIUM CO., LTD.

  公开号：EP2963063A1

  公开（公告）日：2016-01-06

  A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds excluding an aromatic dicarboxylic acid diester into contact with each other to effect a reaction, followed by washing; a second step that brings a tetravalent titanium halide compound and one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction, followed by washing; and a third step that brings one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.

  一种生产烯烃聚合用固体催化剂组分的方法可生产出一种新型的烯烃聚合用固体催化剂组分，该组分具有优异的烯烃聚合活性和聚合过程中对氢的活性，并可生产出具有高MFR、高立体规整度和优异刚性的烯烃聚合物。该方法包括第一步，使镁化合物、四价卤化钛化合物和一种或多种第一内部电子供体化合物（不包括芳香族二羧酸二酯）相互接触以发生反应，然后进行洗涤；第二步，使四价卤化钛化合物和一种或多种第二内部电子供体化合物与第一步得到的产物接触，以发生反应，然后进行洗涤；以及第三步，使一种或多种第三内部电子供体化合物与第二步得到的产物接触，以发生反应。
• SOLID CATALYST COMPONENT FOR POLYMERIZING OLEFINS, CATALYST FOR POLYMERIZING OLEFINS, AND PRODUCTION METHOD FOR POLYMERIZED OLEFINS
  申请人：Toho Titanium Co., Ltd.

  公开号：EP2963062A1

  公开（公告）日：2016-01-06

  A solid catalyst component for olefin polymerization includes titanium, magnesium, a halogen, a compound represented by (R1)kC6H4-k(COOR2)(COOR3), and a compound represented by R4O-C(=O)-O-Z-OR5. The solid catalyst component is a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity.

  一种用于烯烃聚合的固体催化剂组分包括钛、镁、卤素、由(R1)kC6H4-k(COOR2)(COOR3)代表的化合物和由R4O-C(=O)-O-Z-OR5代表的化合物。该固体催化剂组分是一种用于烯烃聚合的新型固体催化剂组分，可在聚合过程中获得优异的烯烃聚合活性和相对于氢的活性，并可生产出具有高 MFR、高立体规整度和优异刚性的烯烃聚合物。
• SOLID CATALYST COMPONENT FOR USE IN POLYMERIZATION OF OLEFINS, METHOD FOR PRODUCING SAME, CATALYST FOR USE IN POLYMERIZATION OF OLEFINS, AND METHOD FOR PRODUCING OLEFIN POLYMER
  申请人：Toho Titanium Co., Ltd.

  公开号：EP3098243A1

  公开（公告）日：2016-11-30

  High stereoregularity, highly active catalytic performance, and good hydrogen response can be obtained by homopolymerizing propylene in the presence of a catalyst that includes a solid catalyst component including titanium, magnesium, a halogen, a carbonate compound represented by the following formula, and a diether compound. Excellent polymerization behavior can also be obtained when effecting random copolymerization or block copolymerization.         R1-O-C(=O)-O-Z-O-R2     (1) wherein R1 and R2 are a hydrocarbon group or a substituted hydrocarbon group having 1 to 24 carbon atoms, or a heteroatom-containing group, provided that R1 and R2 are either identical or different, and Z is a linking group that links two oxygen atoms through a carbon atom or a carbon chain.

  在催化剂（包括钛、镁、卤素、由下式表示的碳酸盐化合物和二醚化合物组成的固体催化剂组分）存在下均聚丙烯，可获得高立体规整度、高活性催化性能和良好的氢响应。在进行无规共聚或嵌段共聚时，也可获得优异的聚合性能。 r1-o-c(=o)-o-z-o-r2 (1) 其中，R1 和 R2 是具有 1 至 24 个碳原子的烃基或取代烃基，或含杂原子的基团，但 R1 和 R2 可以相同或不同；Z 是通过碳原子或碳链连接两个氧原子的连接基团。