过氧化二碳酸双十六酯 | 26322-14-5

• 物质功能分类: 催化剂及助剂 - 引发剂
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 中文名称: 过氧化二碳酸双十六酯
• 中文别名: 过氧化二(十六烷基)二碳酸酯；过氧化二碳酸二-(十六烷基)酯
• 英文名称: di-cetyl peroxydicarbonate
• 英文别名: Dicetyl peroxydicarbonate；hexadecoxycarbonyloxy hexadecyl carbonate
• CAS: 26322-14-5
• 化学式: C₃₄H₆₆O₆
• 分子量: 570.894
• InChiKey: QWVBGCWRHHXMRM-UHFFFAOYSA-N

物化性质

• 熔点：
  52 °C
• 沸点：
  592.2±33.0 °C(Predicted)
• 密度：
  0.936±0.06 g/cm3(Predicted)
• LogP：
  15.1 at 25℃
• 物理描述：
  This solid peroxide is sensitive to heat. Storage of this material must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide with inert solid.

计算性质

• 辛醇/水分配系数(LogP)：
  16.5
• 重原子数：
  40
• 可旋转键数：
  35
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

安全信息

• 危险等级：
  5.2
• 海关编码：
  2909600000
• 包装等级：
  II
• 危险类别：
  5.2

反应信息

• 作为产物：
  描述：

  氯甲酸十六烷基酯 在 sodium peroxide 作用下， 以 乙醚 为溶剂， 反应 0.5h， 生成 过氧化二碳酸双十六酯
  参考文献：
  名称：

  Fomin, V. A., Russian Journal of Applied Chemistry, 1999, vol. 72, # 7, p. 1221 - 1224

  摘要：

  DOI：

文献信息

• Mixtures composed or monocarboxy-functionalized dialkylphosphinic acids, their use and a process for their preparation
  申请人：Maas Wiebke

  公开号：US20070213436A1

  公开（公告）日：2007-09-13

  The invention relates to mixtures composed of monocarboxy-functionalized dialkylphosphinic acids and of further components, which comprise A) from 98 to 100% by weight of monocarboxy-functionalized dialkylphosphinic acids of the formula (I) in which R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 are identical or different and, independently of one another, are H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, and/or phenyl, X and Y are identical or different and, independently of one another, are H, Li, Na, K, or NH 4 , and B) from 0 to 2% by weight of halogens, where the entirety of the components always amounts to 100% by weight.

  该发明涉及由单羧基功能化二烷基膦酸和进一步组分组成的混合物，其中包括 A) 公式（I）中的单羧基功能化二烷基膦酸，其占98至100重量％ 其中R 1 ，R 2 ，R 3 ，R 4 ，R 5 ，R 6 和R 7 相同或不同，并且彼此独立地为H，甲基，乙基，正丙基，异丙基，正丁基，异丁基，叔丁基和/或苯基， X和Y相同或不同，并且彼此独立地为H，Li，Na，K或NH 4 ， 和 B) 卤素，其占0至2重量％， 其中所有组分的总和始终为100重量％。
• METHOD FOR THE PRODUCTION OF ORGANIC PEROXIDES BY MEANS OF A MICROREACTION TECHNIQUE
  申请人：Azzawi Alexander

  公开号：US20090043122A1

  公开（公告）日：2009-02-12

  The invention provides a process for efficient and reliable preparation of organic peroxides, preferably dialkyl peroxides, peroxycarboxylic acids, peroxycarboxylic esters, diacyl peroxides, peroxycarbonate esters, peroxydicarbonates, ketone peroxides and perketals with the aid of at least one static micromixer and an apparatus for performing the process.

  这项发明提供了一种通过至少一个静态微混合器和执行该过程的装置，高效可靠地制备有机过氧化物，优选地为二烷基过氧化物、过氧化羧酸、过氧化羧酸酯、二酰过氧化物、过氧化碳酸酯、过氧二碳酸酯、酮过氧化物和过氧化物的过氧醚的方法。
• Mixtures composed of monocarboxy-functionalized dialkylphosphinic esters and of further components
  申请人：Maas Wiebke

  公开号：US20070210288A1

  公开（公告）日：2007-09-13

  The invention relates to mixtures composed of dialkylphosphinic esters and of further components, which comprise A) from 98 to 100% by weight of monocarboxy-functionalized dialkylphosphinic esters of the formula (I) in which R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 are identical or different and, independently of one another, are H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, and/or phenyl, Y is methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, phenyl, 2-hydroxyethyl, 2,3-dihydroxypropyl, 2-hydroxypropyl, 3-hydroxypropyl, 4-hydroxybutyl, 3-hydroxybutyl, 2-hydroxybutyl, and/or 6-hydroxyhexyl, allyl, and/or glycerol, X is H, Li, Na, K or NH 4 , or X is defined as for Y, and then X and Y are two identical radicals or two different radicals of the above organic radicals, and B) from 0 to 2% by weight of halogens, where the entirety of the components always amounts to 100% by weight.

  该发明涉及由二烷基膦酸酯和进一步组分组成的混合物，其中包括A) 公式（I）的单羧基功能化二烷基膦酸酯，其占98至100重量％，其中R1、R2、R3、R4、R5、R6和R7相同或不同，并且独立地为H、甲基、乙基、正丙基、异丙基、正丁基、异丁基、叔丁基和/或苯基，Y为甲基、乙基、正丙基、异丙基、正丁基、异丁基、叔丁基、苯基、2-羟乙基、2,3-二羟基丙基、2-羟基丙基、3-羟基丙基、4-羟基丁基、3-羟基丁基、2-羟基丁基和/或6-羟基己基、烯丙基和/或甘油，X为H、Li、Na、K或NH4，或者X如Y所定义，然后X和Y是上述有机基团的两个相同基团或两个不同基团，以及B) 卤素，其占0至2重量％，其中所有组分的总和始终为100重量％。
• FUNCTIONALIZED MONOMERS AND POLYMERS
  申请人：DiBiase Stephen Augustine

  公开号：US20120245063A1

  公开（公告）日：2012-09-27

  This invention relates to a composition, comprising: an unsaturated functionalized monomer of from about 5 to about 30 carbon atoms, which is: (a) polymerized to form a functionalized polymer; (b) copolymerized with a comonomer to form a functionalized copolymer; or (c) reacted with an enophilic reagent to form a polyfunctionalized monomer. The polyfunctionalized monomer may be polymerized to form a polyfunctionalized polymer which may be further reacted with one or more additional reagents. The invention relates to lubricants, functional fluids, fuels, dispersants, detergents and polymeric resins.

  这项发明涉及一种组合物，包括：一个由约5至约30个碳原子的不饱和官能化单体组成，该单体：(a)聚合形成官能化聚合物；(b)与共聚单体共聚形成官能化共聚物；或(c)与亲亚烯试剂反应形成多官能单体。多官能单体可以聚合形成多官能聚合物，该聚合物可以进一步与一个或多个额外试剂反应。该发明涉及润滑剂、功能流体、燃料、分散剂、清洁剂和聚合树脂。
• Method for oxidizing hydrocarbons
  申请人：——

  公开号：US20030176733A1

  公开（公告）日：2003-09-18

  The invention relates to a method for oxidizing substrates such as hydrocarbons, waxes or soot. The method involves the use of a compound of formula (I) in which: R1 and R2 represent H, an aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, each having 1 to 20 hydrocarbon atoms, SO3H, NH2, OH, F, Cl, Br, I and/or NO2, whereby R1 and R2 designate identical or different radicals or R1 and R2 can be linked to one another via a covalent bonding; Q1 and Q2 represent C, CH, N, CR5, each being the same or different; X and Z represent C, S, CH2, each being the same or different; Y represents O and OH; k=0, 1, 2; l=0, 1, 2; m=1 to 3, and; R5 represents one of the meanings of R1. Said compound is used as a catalyst in the presence of a radical initiator, whereby the molar ratio of the catalyst to the hydrocarbon is less than 10 mol %. Peroxy compounds or azo compounds can be used as the radical initiator. Preferred substrates are aliphatic or aromatic hydrocarbons.

  该发明涉及一种氧化底物（如烃、蜡或烟尘）的方法。该方法涉及使用式（I）的化合物，其中：R1和R2代表H、脂肪或芳香烷氧基基、羧基、烷氧羰基基或烃基，每个基有1到20个碳氢原子，SO3H、NH2、OH、F、Cl、Br、I和/或NO2，其中R1和R2表示相同或不同的基团，或者R1和R2可以通过共价键相连；Q1和Q2代表C、CH、N、CR5，每个基相同或不同；X和Z代表C、S、CH2，每个基相同或不同；Y代表O和OH；k=0、1、2；l=0、1、2；m=1到3；R5代表R1的一种含义。所述化合物作为催化剂在自由基引发剂存在下使用，其中催化剂与烃的摩尔比小于10mol％。过氧化物或偶氮化合物可用作自由基引发剂。首选底物为脂肪或芳香烃。