2-Cyan-3-<4-tolyl>-acrylsaeure | 80540-68-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: 2-Cyan-3-<4-tolyl>-acrylsaeure
• 英文别名: 2-Cyano-3-(4-methylphenyl)prop-2-enoic acid
• CAS: 80540-68-7
• 化学式: C₁₁H₉NO₂
• mdl: MFCD01313927
• 分子量: 187.198
• InChiKey: VSMAAVBAABUVMQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  61.1
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-Cyan-3-<4-tolyl>-acrylsaeure 、 双氢青蒿素 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 8.0h， 以54%的产率得到
  参考文献：
  名称：

  Discovery of novel dihydroartemisinin-cinnamic hybrids inducing lung cancer cells apoptosis via inhibition of Akt/Bad signal pathway

  摘要：

  DOI：

  10.1016/j.bioorg.2021.104903
• 作为产物：
  描述：

  对甲基苯甲醛 、 氰乙酸 生成 2-Cyan-3-<4-tolyl>-acrylsaeure
  参考文献：
  名称：

  Fiquet, Annales de Chimie (Cachan, France), 1893, vol. <6> 29, p. 439

  摘要：

  DOI：

文献信息

• Restriction of Molecular Twisting on a Gold Nanoparticle Surface
  作者：Tushar Debnath、Jayanta Dana、Partha Maity、Hyacintha Lobo、Ganapati S. Shankarling、Hirendra N. Ghosh

  DOI：10.1002/chem.201500044

  日期：2015.4.7

  intramolecular charge transfer (ICT) and twisted intramolecular charge transfer (TICT) states on a gold nanoparticle (Au NP) surface, we have designed and synthesized a new coumarin molecule (C3) that exists both as ICT and TICT states in its excited state in a polar environment. On a Au NP surface, an excited C3 molecule only exists as an ICT state owing to restricted molecular rotation of a diethylamino group;

  为了了解金纳米粒子（Au NP）表面上分子内电荷转移（ICT）和扭曲的分子内电荷转移（TICT）态的光物理性质，我们设计并合成了同时以ICT和TICT形式存在的新香豆素分子（C3）在极性环境中处于激发态。在Au NP表面上，由于二乙氨基的分子旋转受限制，被激发的C3分子仅以ICT状态存在。结果，未观察到从ICT到TICT状态的转换。具有双发射态的分子的优先态的选择对于选择的生物学应用可能是有帮助的。
• Silver halide photographic light-sensitive material containing
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04645735A1

  公开（公告）日：1987-02-24

  A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having positioned thereon a light-sensitive silver halide emulsion layer, a light-insensitive layer and ultraviolet ray absorbing polymer latex of a polymer having a repeating unit derived from a monomer represented by the general formula (I): ##STR1## within general formula (I) the substituents are defined within the specification. The Q represents an ultraviolet ray absorbing group represented by a general formula (II) or (III): ##STR2## The substituents within the general formulae given above are defined in the specification. By including the particular ultraviolet ray absorbing polymer latex of the invention the resulting photographic material has improved antistatic properties and the photographic characteristics of the material are not deteriorated by the presence of the latex.

  本发明公开了一种银卤片光敏材料。该材料包括一个支撑基材，其上放置有一层光敏银卤乳胶层、一层不敏感于光的层和一种聚合物乳胶的紫外线吸收剂，该聚合物具有由一种单体表示的重复单元导出的重复单元，该单体由通式（I）表示：##STR1## 公式（I）中，取代基在规范中定义。Q表示由通式（II）或（III）表示的紫外线吸收基团：##STR2## 上述通式中的取代基在规范中定义。通过包含本发明的特定紫外线吸收聚合物乳胶，得到的照相材料具有改善的抗静电性能，并且材料的照相特性不会因乳胶的存在而恶化。
• Silver halide photographic light-sensitive element containing a u.v.
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04431726A1

  公开（公告）日：1984-02-14

  A silver halide photographic light-sensitive material is disclosed. The material is comprised of one or more light-sensitive silver emulsion layers and one or more light-insensitive layers. The silver halide layers or light-insensitive layers contain an ultraviolet ray absorbing polymer latex. The polymer latex is comprised of a homopolymer or copolymer having a repeating unit derived from monomers represented by the following general formula (I): ##STR1## wherein the substituents within a general formula (I) are defined within the specification. The polymer latex (I) contains a substituents Q which represents an ultraviolet ray absorbing group represented by the general formula (II): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, an arylthio group having 6 to 20 carbon atoms, an amino group, an alkylamino group having 1 to 20 carbon atoms, an arylamino group having 6 to 20 carbon atoms, a hydroxyl group, a cyano group, a nitro group, an acylamino group, a carbamoyl group, a sulfonyl group, a sulfamoyl group, a sulfonamide group, an acyloxy group or an oxycarbonyl group, and R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 may form a 5 to 6 member ring by ring closure; R.sub.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R.sub.7 represents a cyano group, --COOR.sub.9, --CONHR.sub.9, --COR.sub.9 or --SO.sub.2 R.sub.9 ; and R.sub.8 represents a cyano group, --COOR.sub.10, --CONHR.sub.10, --COR.sub.10 or --SO.sub.2 R.sub.10 ; wherein R.sub.9 and R.sub.10 each represents an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms; wherein one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 bonds to the vinyl group through the linking group. The photographic material which includes the polymer latex of the invention has excellent absorption characteristics in the 300 to 400 nm range and does not cause static marks caused by ultraviolet rays. Furthermore, the material does not undergo deterioration of color reproduction and fading or discoloration of color images caused by light.

  本发明公开了一种银卤光敏感材料。该材料由一个或多个光敏银乳胶层和一个或多个光不敏感层组成。银卤层或光不敏感层含有一种紫外线吸收聚合物乳胶。该聚合物乳胶由一个重复单元来自于下述通式（I）的单体的均聚物或共聚物组成：##STR1##其中，通式（I）中的取代基在规范内有定义。聚合物乳胶（I）包含一种取代基Q，该取代基Q表示由下述通式（II）表示的紫外线吸收基团：##STR2##其中，R.sub.1、R.sub.2、R.sub.3、R.sub.4和R.sub.5分别表示氢原子、卤素原子、具有1至20个碳原子的烷基、具有6至20个碳原子的芳基、具有1至20个碳原子的烷氧基、具有6至20个碳原子的芳氧基、具有1至20个碳原子的烷硫基、具有6至20个碳原子的芳硫基、氨基、具有1至20个碳原子的烷基氨基、具有6至20个碳原子的芳基氨基、羟基、氰基、硝基、酰胺基、氨基甲酰基、磺酰基、磺酰胺基、磺酰胺基、酰氧基或氧羰基，且R.sub.1和R.sub.2、R.sub.2和R.sub.3、R.sub.3和R.sub.4或R.sub.4和R.sub.5可以通过环闭合形成5至6个成员环；R.sub.6表示氢原子或具有1至20个碳原子的烷基；R.sub.7表示氰基、--COOR.sub.9、--CONHR.sub.9、--COR.sub.9或--SO.sub.2R.sub.9；以及R.sub.8表示氰基、--COOR.sub.10、--CONHR.sub.10、--COR.sub.10或--SO.sub.2R.sub.10；其中，R.sub.9和R.sub.10分别表示具有1至20个碳原子的烷基或具有6至20个碳原子的芳基；其中，R.sub.1、R.sub.2、R.sub.3、R.sub.4、R.sub.5、R.sub.6、R.sub.7和R.sub.8中的一个通过连接基与乙烯基结合。本发明的聚合物乳胶所包含的摄影材料在300至400纳米范围内具有优异的吸收特性，不会引起紫外线产生的静电痕迹。此外，该材料不会因光线而导致色彩再现的恶化和色彩图像的褪色或变色。
• Silver halide photographic light-sensitive material
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04464462A1

  公开（公告）日：1984-08-07

  A silver halide photographic light-sensitive material having improved antistatic properties is disclosed. The material is comprised of a support having thereon a light-senstive silver halide emulsion layer and a light-insensitive layer. The material includes (A) a flourine containing cationic surface active agent and (B) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## within the formula (I) the Q is an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR2## the substituents within the formulae shown are defined within the specification. The ultraviolet ray absorbing polymer latex is present in the material in an amount in the range of 10 to 2,000 mg/m.sup.2 of the material. The material which contains a combination of the ultraviolet ray absorbing polymer latex and the fluorine containing cationic surface active agent has excellent antistatic properties and does not result in the occurrence of pressure marks.

  本发明揭示了一种具有改进的抗静电性能的银卤素照相感光材料。该材料包括具有光敏银卤素乳液层和光不敏感层的支撑体。该材料包括（A）含氟阳离子表面活性剂和（B）紫外线吸收聚合物乳液，该聚合物或共聚物具有由以下通式（I）所表示的单体导出的重复单元：##STR1##其中，Q是由以下通式（II）或（III）所表示的紫外线吸收基团：##STR2##所示的取代基在说明书中定义。紫外线吸收聚合物乳液以10至2,000 mg/m.sup.2的材料的范围存在于该材料中。该材料包含紫外线吸收聚合物乳液和含氟阳离子表面活性剂的组合具有优异的抗静电性能且不会产生压力印记。
• Silver halide photographic light-sensitive material containing a UV
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04455368A1

  公开（公告）日：1984-06-19

  A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion and at least one light-insensitive layer is disclosed. One or more of the layers of the material contains an ultraviolet ray absorbing polymer latex which comprises a homopolymer or copolymer having a repeating unit derived from a monomer represented by the general formula (II) in which one or more ultraviolet ray absorbing compounds represented by the general formula (I) is loaded: ##STR1## the substituents within the general formula are defined within the specification. The material has excellent absorption characteristics in the 300 to 400 nm range and does not cause static marks caused by ultraviolet rays or undergo deterioration of color reproduction. In addition, the material has good film strength and reduced layer thickness and provides a color image having improved sharpness which is free from fading or discoloration due to light.

  本发明揭示了一种含有至少一种感光性银卤化物乳液和至少一层不敏感于光的层的支撑物的银卤化物摄影感光材料。该材料的一层或多层含有一种紫外线吸收聚合物乳液，其包含一个由单体通式（II）表示的重复单元的均聚物或共聚物，其中装载了一个或多个通式（I）表示的紫外线吸收化合物：##STR1## 通式中的取代基在规范中有定义。该材料在300至400纳米范围内具有优异的吸收特性，不会引起紫外线引起的静电印记或色彩再现的恶化。此外，该材料具有良好的膜强度和降低的层厚度，并提供具有改善锐度的彩色图像，无褪色或因光线而变色。