8-hydroxyquinoline phosphate | 21288-28-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 8-hydroxyquinoline phosphate
• 英文别名: quinolin-8-ol; dihydrogenphosphate；Chinolin-8-ol; Dihydrogenphosphat；8-Quinolinol, phosphate (salt)；phosphoric acid;quinolin-8-ol
• CAS: 21288-28-8
• 化学式: C₉H₇NO*H₃O₄P
• 分子量: 243.156
• InChiKey: QTLGWYAJVCWZFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.01
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  111
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  8-羟基喹啉 在 磷酸 作用下， 以 乙醇 为溶剂， 反应 4.5h， 生成 8-hydroxyquinoline phosphate
  参考文献：
  名称：

  四种新型的带有8-羟基喹啉阳离子的布朗斯台德酸性离子液体在六种醇中的溶解度

  摘要：

  四种新型布朗斯台德酸性离子液体（8-羟基喹啉磷酸盐（[HOQu] [H 2 PO 4 ]），硫酸8-羟基喹啉硫酸盐（[HOQu] [HSO 4 ]），8-羟基喹啉甲烷磺酸盐（[HOQu]）的平衡溶解度[CH 3 SO 3 ]）和8-羟基喹啉对甲苯磺酸盐（[HOQu] [ p使用静态方法在（278.15至348.15）K的温度下测量了六种低级醇（甲醇，乙醇，1-丙醇，2-丙醇，1-丁醇和2-甲基-1-丙醇）中的-TSA]））。随着温度的升高，离子液体的溶解度增加，其中一些显示出“温度敏感”特性。离子液体的溶解度与溶剂的极性和分子结构以及离子液体的阴离子基团和醇之间的氢键强度密切相关。通过修改的Apelblat方程和λh方程可以很好地关联实验溶解度值。溶解焓（Δdisoln S）和溶解熵（Δdisoln H）用van't Hoff方程确定），并在T  = 298.15 K时计算吉布斯自由能（Δdisoln

  DOI：

  10.1016/j.molliq.2016.04.015

文献信息

• POLYORGANOSILOXANE EMULSION, PROCESS FOR PRODUCING THE SAME, AND MATERIAL FOR COSMETIC PREPARATION
  申请人：Dow Corning Toray Silicone Co., Ltd.

  公开号：EP1394215A1

  公开（公告）日：2004-03-03

  A polyorganosiloxane emulsion comprising (A) polyorganosiloxane, (B) N-acylalkyltaurine and/or a salt thereof, and (C) water, the aforementioned emulsion having an average particle diameter of 0.15 µm or more; a method of preparation of the polyorganosiloxane emulsion, characterized by subjecting a polyorganosiloxane (a) having a molecular weight lower than that of component (A), to emulsification polymerization in water in the presence of (B) N-acylalkyltaurine and/or a salt thereof; and a cosmetic raw material comprising the aforementioned polyorganosiloxane emulsion. The cosmetic raw material of the invention possesses excellent cosmetic functionalities such as wettability, smoothness, and good affinity to skin and hair. Furthermore, it is characterized by good stability in storage and compounding stability in combination with our cosmetic raw materials.

  一种聚有机硅氧烷乳液，包括(A)聚有机硅氧烷，(B)N-酰基烷基牛磺酸和/或其盐，和(C)水，上述乳液的平均颗粒直径为0.15 µm 或以上；一种聚有机硅氧烷乳液的制备方法，其特征在于将分子量低于组分(A)的聚有机硅氧烷(a)在(B)N-酰基烷基嘌呤和/或其盐存在下在水中进行乳化聚合；以及一种包含上述聚有机硅氧烷乳液的化妆品原料。本发明的化妆品原料具有出色的化妆品功能，如润湿性、平滑性以及与皮肤和头发的良好亲和性。此外，它还具有良好的贮存稳定性，以及与我们的化妆品原料配合使用时的复配稳定性。
• AQUEOUS SUSPENSION OF CROSSLINKED SILICONE PARTICLES, AQUEOUS EMULSION OF OIL CONTAINING CROSSLINKED SILICONE PARTICLES, AND COSMETIC INGREDIENTS
  申请人：Dow Corning Toray Silicone Company, Ltd.

  公开号：EP1541633A1

  公开（公告）日：2005-06-15

  Aqueous suspensions of cross-linked silicone particles comprising : (A) cross-linked silicone particles with an average particle size of from 0.1 to 500 µm, (B) N-acyl-, N-hydrocarbon taurines and/or their salts, and (C) water, aqueous emulsions of oil containing cross-linked silicone particles comprising : (A) cross-linked silicone particles with an average particle size of from 0.1 to 500 µm, (D) oil, (B) N-acyl-, N-hydrocarbon taurines and/or their salts, and (C) water, with component (A) contained in droplets of component (D) dispersed in water, and cosmetic raw materials comprising said aqueous suspensions or said aqueous emulsions. The suspensions and emulsions are characterized by superior stability and by low environmental impact and minimal effects on the human body. In addition, they are extremely useful as cosmetic raw materials because of their superior cosmetics functionality such as wetness and smoothness.

  交联有机硅颗粒的水悬浮液，包括：(A)平均粒径为 0.1 至 500 微米的交联有机硅颗粒，(B)N-酰基-、N-烃基牛磺酸和/或其盐，以及(C)水；含有交联有机硅颗粒的油的水乳液，包括：(A)平均粒径为 0.1至500微米的交联有机硅颗粒，(D)油，(B)N-酰基、N-烃基牛磺酸和/或其盐，以及(C)水，其中组分(A)包含在分散于水中的组分(D)的液滴中，以及包含所述水性悬浮液或所述水性乳液的化妆品原料。这些悬浮液和乳液具有优异的稳定性，对环境的影响较小，对人体的影响也最小。此外，它们作为化妆品原料也非常有用，因为它们具有卓越的化妆品功能，如润湿性和柔滑性。
• Oil-in-water type organopolysiloxane emulsion and method for producing same, cosmetic raw material, and cosmetic product
  申请人：Dow Corning Toray Co., Ltd.

  公开号：US10959937B2

  公开（公告）日：2021-03-30

  Disclosed is an oil-in-water type organopolysiloxane emulsion that is stable and has smaller particle diameters for a long period of time even in cases where a low-polarity organopolysiloxane and a cationic surfactant are used. The emulsion comprises: (A) 100 parts by weight of a diorganopolysiloxane having a viscosity of 2 to 100,000 mPa·s at 25° C., (B) 0.5 to 30 parts by weight of a cationic surfactant, (C) 0.1 to 10 parts by weight of a nonionic surfactant, and (D) 11 to 550 parts by weight of water, wherein a content of component (C) is equal to or less than a content of component (B), and wherein an average particle diameter of component (A) in the emulsion is 600 nm or less. Related methods and cosmetics are also disclosed.

  本发明公开了一种水包油型有机聚硅氧烷乳液，即使在使用低极性有机聚硅氧烷和阳离子表面活性剂的情况下，该乳液也能长期保持稳定并具有较小的颗粒直径。该乳液包括：(A) 100 重量份的二甘醇聚硅氧烷，其在 25 摄氏度时的粘度为 2 至 100,000 mPa-s、(B) 0.5 至 30 份（按重量计）阳离子表面活性剂， (C) 0.1 至 10 份（按重量计）非离子表面活性剂，以及 (D) 11 至 550 份（按重量计）水，其中组分 (C) 的含量等于或小于组分 (B) 的含量，乳液中组分 (A) 的平均颗粒直径为 600 nm 或更小。还公开了相关的方法和化妆品。
• Polyorganosiloxane emulsions,process for producing the same and material for cosmetic preparation
  申请人：——

  公开号：US20040091438A1

  公开（公告）日：2004-05-13

  A polyorganosiloxane emulsion comprising (A) polyorganosiloxane, (B) N-acylalkyltaurine, salts thereof, and combinations thereof, and (C) water, the aforementioned emulsion having an average particle diameter of 0.15 &mgr;m or or greater; a method of preparation of the polyorganosiloxane emulsion, characterized by subjecting a polyorganosiloxane (a) having a molecular weight lower than that of component (A), to emulsification polymerization in water in the presence of component (B), and a cosmetic raw material comprising the aforementioned polyorganosiloxane emulsion. The cosmetic raw material of the invention possesses excellent cosmetic functionalities such as wettability, smoothness, and good affinity to skin and hair. Furthermore, it is characterized by good stability in storage and compounding stability in combination with other cosmetic raw materials.

  一种聚有机硅氧烷乳液，包括(A)聚有机硅氧烷，(B)N-酰基烷基牛磺酸、其盐和其组合物，和(C)水，上述乳液的平均颗粒直径为0.15&mgr;m或更大；一种聚有机硅氧烷乳液的制备方法，其特征在于将分子量低于组分(A)的聚有机硅氧烷(a)在组分(B)存在下在水中进行乳化聚合，以及一种包含上述聚有机硅氧烷乳液的化妆品原料。本发明的化妆品原料具有优异的化妆品功能，如润湿性、平滑性以及与皮肤和头发的良好亲和性。此外，它还具有良好的储存稳定性以及与其他化妆品原料混合使用时的复配稳定性。
• Polyorganosiloxane emulsion composition and a cosmetic material made therefrom
  申请人：——

  公开号：US20040138373A1

  公开（公告）日：2004-07-15

  A polyorganosiloxane emulsion composition characterized by comprising (A) a polyorganosiloxane, (B) an N-acylalkyl taurine and/or a salt thereof, and (C) water, the content of cyclic organosiloxane oligomers in said component (A) being within 3.5 wt. %, and a cosmetic raw material characterized by consisting of said polyorganosiloxane emulsion composition. The emulsion composition is characterized by superior cosmetic functionality in terms of moisture and smoothness.

  一种聚有机硅氧烷乳液组合物，其特征在于包括（A）一种聚有机硅氧烷，（B）一种 N-酰基烷基牛磺酸和/或其盐，以及（C）水，所述组分（A）中环状有机硅氧烷低聚物的含量在 3.5 重量％以内，以及一种化妆品原料，其特征在于由所述聚有机硅氧烷乳液组合物组成。该乳液组合物的特点是在保湿和柔滑性方面具有卓越的化妆品功能。