4-(8-hydroxyoctyloxy)-4'-cyanobiphenyl | 132102-86-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(8-hydroxyoctyloxy)-4'-cyanobiphenyl
• 英文别名: 4-hydroxyoctyloxy-4'-cyanobiphenyl；4'-(8-hydroxyoctyloxy)biphenyl-4-carbonitrile；4-[4-(8-hydroxyoctoxy)phenyl]benzonitrile
• CAS: 132102-86-4
• 化学式: C₂₁H₂₅NO₂
• 分子量: 323.435
• InChiKey: UDZMENXOYXYYMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  24
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  53.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(8-hydroxyoctyloxy)-4'-cyanobiphenyl 在 caesium carbonate 、 三乙胺 、 lithium bromide 作用下， 以 氯仿 、 丙酮 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  액정 화합물 및 이를 포함하는 쌍안정 액정 패널

  摘要：

  本申请涉及液晶化合物、包括其在双稳态液晶面板中的应用及其用途。根据本申请的液晶化合物可在形成液晶层的液晶组分中包含，能够提供适合双稳态液晶面板应用的相变温度和导电性质。这种液晶化合物可以应用于双稳态液晶面板和包括该面板的各种光调制装置等，以降低驱动电压。

  公开号：

  KR102069479B1
• 作为产物：
  描述：

  1,8-辛二醇 在 氢溴酸 、 potassium carbonate 作用下， 以 水 、 丙酮 、 甲苯 为溶剂， 反应 96.0h， 生成 4-(8-hydroxyoctyloxy)-4'-cyanobiphenyl
  参考文献：
  名称：

  Influence of liquid crystalline formation on the phase behavior of side-chain liquid crystalline block copolymers

  摘要：

  A series of narrowly distributed diblock copolymers composed of amorphous components and side-chain liquid crystalline (LC) polymer, poly (butyl acrylate)-block-poly [8-(4-cyano-4'-biphenyl)-1-octanoyl acrylate] (PBA-b-PCBOA), with side-chain LC block weight fraction (f(w,PCBOA)) ranging from 25% to 87%, were synthesized by atom transfer radical polymerization (ATRP). Their thermal property, LC behavior, bulk phase behavior and thin film morphology were studied by differential scanning calorimetry (DSC), polarizing optical microscope (POM), small-angle X-ray scattering (SAXS) techniques and atomic force microscopy (AFM), respectively. The results show the diblock copolymers with different composition could present sphere, lamellar and cylinder morphologies before the order disorder transition. As the mesogen units self-organize to form smectic phase, the lamellar morphology dominates during the majority LC block weight fraction range (f(w,PCBOA) = 46%-77%) to minimized the surface energy. Interestingly, for spin-coated thin film, the lamella phase separation size decreased with increasing annealing time. For the copolymer with f(w,PCBOA) of 67%, a thermoreversible order order transition (OOT) and lamella to lamella/modified layer (L/ML), were observed. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2015.01.077

文献信息

• Blue Luminescent Naphthalene-based Liquid Crystals
  作者：Takeshi Mori、Masashi Kijima

  DOI：10.1246/cl.2007.710

  日期：2007.6.5

  Novel luminescent liquid crystals were synthesized by introducing a mesogenic cyanobiphenylyl side chain to a luminescent naphthalene core. The 1,5-naphthalene derivatives were thermotropic liquid crystals showing monotropic phase transition, while 2,6-naphthalene derivatives showed an enantiotropic behavior. All compounds had an intense bluish emission in the solid, liquid crystal, and isotropic liquid states, which was investigated by UV–vis and PL spectroscopies.

  通过将一种介质性氰基联苯侧链引入发光萘核心，合成了新型发光液晶。1,5-萘衍生物是具有单调相变的热致液晶，而2,6-萘衍生物则表现出外消旋行为。所有化合物在固态、液晶态和各向同性液态下均具有强烈的蓝色发光，这通过紫外-可见光和荧光光谱进行了研究。
• Preparation and thermal properties of 4-alkoxy-4′-cyanobiphenyl esters of ferrocene dicarboxylic acid
  作者：J. Bhatt、B.M. Fung、Kenneth M. Nicholas

  DOI：10.1016/0022-328x(91)80055-o

  日期：1991.8

  1′-diesters 2a–e incorporating variable length alkoxycyanobiphenyl units have been prepared and their melting behavior has been examined. Whereas 2a, b, d (n = 3, 4, 8, respectively) display normal melting properties, 2c (n = 6) and 2e (n = 10) both exhibit polymorphism in the solid state and 2e has a smectic phase between 85 and 88°C.

  一系列新的介晶二茂铁基-1,1'-二酯2a – e结合了可变长度的烷氧基氰基联苯单元，并已对其熔融行为进行了研究。而2a，b，d（分别为n = 3、4、8）显示出正常的熔融特性，而2c（n = 6）和2e（n = 10）都显示出固态多态性，而2e的近晶相在85之间和88°C。
• Photo cross-linkable liquid crystal derivatives
  申请人：Rolic AG

  公开号：US05800733A1

  公开（公告）日：1998-09-01

  The present invention is concerned with photo cross-linkable liquid crystalline compounds in the formula ##STR1## wherein for example: A,B,C,D,E,F independently is pyridine-2,5-diyl, pyrimidine-2,5-diyl, trans-1,4-cyclohexylene, trans-1,3-dioxane-2,5-diyl Z.sup.1, Z.sup.2, Z.sup.7 independently is --(CH.sub.2).sub.s O--, --COO--, --(CH.sub.2).sub.s COO-- Z.sup.3, Z.sup.4, Z.sup.8 independently is a single bond, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O-- Z.sup.5, Z.sup.6 independently is --(CH.sub.2).sub.s -- m, n, q and r independently is 0, 1 or 2; s is a whole number of 1 to 16; R.sup.1, R.sup.2 independently is CH.sub.2 .dbd.CH--COO--, CH.sub.2 .dbd.C(CH.sub.3)--COO-- R.sup.3 is H, CH, COOC.sub.n H.sub.2n+1, CnH.sub.2n+1 ; n=1 . . . 10 X.sup.1, X.sup.2 and X.sup.3 independently is hydrogen, halogen, cyano or lower alkyl. The invention is also related to liquid crystalline mixtures and their use for electro-optical purpose.

  本发明涉及公式##STR1##中的光交联液晶化合物，其中例如：A，B，C，D，E，F独立地是吡啶-2,5-二基苯，嘧啶-2,5-二基苯，反-1,4-环己烷基，反-1,3-二氧六环-2,5-二基苯Z.sup.1，Z.sup.2，Z.sup.7独立地是--(CH.sub.2).sub.s O--，--COO--，--(CH.sub.2).sub.s COO--Z.sup.3，Z.sup.4，Z.sup.8独立地是单键，--CH.sub.2 CH.sub.2 --，--CH.sub.2 O--Z.sup.5，Z.sup.6独立地是--(CH.sub.2).sub.s--m，n，q和r独立地是0，1或2；s是1到16的整数；R.sup.1，R.sup.2独立地是CH.sub.2.dbd.CH--COO--，CH.sub.2.dbd.C(CH.sub.3)--COO--R.sup.3是H，CH，COOC.sub.n H.sub.2n+1，CnH.sub.2n+1；n=1 . . . 10 X.sup.1，X.sup.2和X.sup.3独立地是氢，卤素，氰基或低烷基。本发明还涉及液晶混合物及其用于电光目的的使用。
• Potochromic liquid crystals
  申请人：Frigoli Michel

  公开号：US20050258396A1

  公开（公告）日：2005-11-24

  The invention relates to novel photochromic liquid crystal materials which may be used in various electro-optic devices including liquid crystal devices. The materials can be converted into another form on irradiation by light which may make it feasible for them to be addressed by light in electro-optic devices. The materials are based on 5-membered heterocycles.

  本发明涉及一种新型光致变色液晶材料，可用于各种电光器件，包括液晶器件。这些材料可以在受到光照射后转化为另一种形式，这使得它们可以被光地址化在电光器件中使用。这些材料基于5元杂环。
• Hierarchically Structured Nanocomposites via Mixed-Graft Block Copolymer Templating: Achieving Controlled Nanostructure and Functionality
  作者：Yazhen Xue、Qingliang Song、Yuchu Liu、Daniel Smith、Weihua Li、Mingjiang Zhong

  DOI：10.1021/jacs.3c10297

  日期：2024.1.10

  for crafting nanostructured polymer–inorganic composites, leveraging hierarchically assembling mixed-graft block copolymers (mGBCPs) as templates. These mGBCPs, composed of diverse polymeric side chains that are covalently tethered with a defined sequence to a linear backbone polymer, self-assemble into ordered hierarchical structures with independently tuned nano- and mesoscale lattice features. Through

  整合无机和聚合有机功能来创建复合材料为多功能材料的发现和制造提供了有效的策略。这些复合材料的特性超出了单个组件特性的简单总和；它们受到这些组件的空间排列以及由此产生的同质/异质相互作用的深刻影响。在这项工作中，我们开发了一种简便且高度适应性的方法，利用分层组装的混合接枝嵌段共聚物（mGBCP）作为模板来制造纳米结构聚合物-无机复合材料。这些 mGBCP 由不同的聚合物侧链组成，这些侧链以定义的序列共价连接到线性主链聚合物上，自组装成有序的分层结构，具有独立调节的纳米和介观晶格特征。通过将 mGBCP 与不同尺寸的无机填料（例如金属离子（约 0.1 nm）、金属氧化物簇（0.5-2 nm）和金属纳米粒子（> 2 nm））共组装，我们创建了具有受控中间填料的三维填料阵列分离和安排。通过在不同填料和 mGBCP 侧链之间引入正交相互作用，多种类型的无机填料同时集成到 mGBCP 基质中。这产生了