3-Methyl-4-propyloxetan-2-one | 412274-90-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 3-Methyl-4-propyloxetan-2-one
• 英文别名: 3-methyl-4-propyloxetan-2-one
• CAS: 412274-90-9
• 化学式: C₇H₁₂O₂
• 分子量: 128.171
• InChiKey: ICGHDFCPUNUZNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-Methyl-4-propyloxetan-2-one 、 苯甲醇 在 lipase PS (Pseudomonas Sp_.) 作用下， 以 丙酮 为溶剂， 反应 264.0h， 生成 (3R,4R)-trans-3-Methyl-4-propyloxetan-2-one 、 Benzyl (2R,3R)-2-methyl-3-hydroxyhexanoate 、 Benzyl (2S,3S)-2-methyl-3-hydroxyhexanoate
  参考文献：
  名称：

  Sakai, Naoko; Ageishi, Satoru; Isobe, Hiroshi, Journal of the Chemical Society. Perkin transactions I, 2000, # 1, p. 71 - 78

  摘要：

  DOI：
• 作为产物：
  描述：

  3-hydroxy-2-methylhexanoic acid 在 吡啶 、 对甲苯磺酰氯 作用下， 生成 3-Methyl-4-propyloxetan-2-one
  参考文献：
  名称：

  Sakai, Naoko; Ageishi, Satoru; Isobe, Hiroshi, Journal of the Chemical Society. Perkin transactions I, 2000, # 1, p. 71 - 78

  摘要：

  DOI：

文献信息

• Direct Acylation of Carrier Proteins with Functionalized β-Lactones
  作者：Jon W. Amoroso、Lawrence S. Borketey、Gitanjeli Prasad、Nathan A. Schnarr

  DOI：10.1021/ol100684s

  日期：2010.5.21

  As the key component of many biosynthetic assemblies, acyl-carrier proteins offer a robust entry point for introduction of small molecule probes and pathway intermediates. Current labeling strategies primarily rely on modifications to the phosphopantetheine cofactor or its biosynthetic precursors followed by attachment to the apo form of a given carrier protein. As a greatly simplified alternative, direct and selective acylation of holo-acyl-carrier proteins using readily accessible beta-lactones as electrophilic partners for the phosphopantetheine-thiol has been demonstrated.
• Radiation hardened composite layer plate or film
  申请人：Gruber Nick

  公开号：US20070166548A1

  公开（公告）日：2007-07-19

  The invention relates to a radiation-curable laminated sheet or film comprising at least one substrate layer and a top layer which comprises a radiation-curable material having a glass transition temperature below 50° C. and having a high double bond density, processes for the production thereof and the use thereof.
• US7955538B2
  申请人：——

  公开号：US7955538B2

  公开（公告）日：2011-06-07
• Sakai, Naoko; Ageishi, Satoru; Isobe, Hiroshi, Journal of the Chemical Society. Perkin transactions I, 2000, # 1, p. 71 - 78
  作者：Sakai, Naoko、Ageishi, Satoru、Isobe, Hiroshi、Hayashi, Yoshiyuki、Yamamoto, Yukio

  DOI：——

  日期：——